Traditional real-time air quality monitoring instruments are expensive to install and maintain; therefore, such existing air quality monitoring networks are sparsely deployed and lack the measurement density to develop high-resolution spatiotemporal air pollutant maps. More recently, low-cost sensors have been used to collect high-resolution spatial and temporal air pollution data in real-time. In this paper, for the first time, Envirowatch E-MOTEs are employed for air quality monitoring as a case study in Sheffield. Ten E-MOTEs were deployed for a year (October 2016 to September 2017) monitoring several air pollutants (NO, NO2, CO) and meteorological parameters. Their performance was compared to each other and to a reference instrument installed nearby. E-MOTEs were able to successfully capture the temporal variability such as diurnal, weekly and annual cycles in air pollutant concentrations and demonstrated significant similarity with reference instruments. NO2 concentrations showed very strong positive correlation between various sensors. Mostly, correlation coefficients (r values) were greater than 0.92. CO from different sensors also had r values mostly greater than 0.92; however, NO showed r value less than 0.5. Furthermore, several multiple linear regression models (MLRM) and generalised additive models (GAM) were developed to calibrate the E-MOTE data and reproduce NO and NO2 concentrations measured by the reference instruments. GAMs demonstrated significantly better performance than linear models by capturing the non-linear association between the response and explanatory variables. The best GAM developed for reproducing NO2 concentrations returned values of 0.95, 3.91, 0.81, 0.005 and 0.61 for factor of two (FAC2), root mean square error (RMSE), coefficient of determination (R2), normalised mean biased (NMB) and coefficient of efficiency (COE), respectively. The low-cost sensors offer a more affordable alternative for providing real-time high-resolution spatiotemporal air quality and meteorological parameter data with acceptable performance.

Abstract-The performance of matrix completion based recovery of missing data in electricity distribution systems is analyzed. Under the assumption that the state variables follow a multivariate Gaussian distribution the matrix completion recovery is compared to estimation and information theoretic limits. The assumption about the distribution of the state variables is validated by the data shared by Electricity North West Limited. That being the case, the achievable distortion using minimum mean square error (MMSE) estimation is assessed for both random sampling and optimal linear encoding acquisition schemes. Within this setting, the impact of imperfect second order source statistics is numerically evaluated. The fundamental limit of the recovery process is characterized using Rate-Distortion theory to obtain the optimal performance theoretically attainable. Interestingly, numerical results show that matrix completion based recovery outperforms MMSE estimator when the number of available observations is low and access to perfect source statistics is not available.

The advanced operation of future electricity distribution systems is likely to require significant observability of the different parameters of interest (e.g., demand, voltages, currents, etc.). Ensuring completeness of data is, therefore, paramount. In this context, an algorithm for recovering missing state variable observations in electricity distribution systems is presented. The proposed method exploits the low rank structure of the state variables via a matrix completion approach while incorporating prior knowledge in the form of second order statistics. Specifically, the recovery method combines nuclear norm minimization with Bayesian estimation. The performance of the new algorithm is compared to the information-theoretic limits and tested trough simulations using real data of an urban low voltage distribution system. The impact of the prior knowledge is analyzed when a mismatched covariance is used and for a Markovian sampling that introduces structure in the observation pattern. Numerical results demonstrate that the proposed algorithm is robust and outperforms existing state of the art algorithms.

Two air pollutants, oxides of nitrogen (NOx) and particulate matter (PM10), are monitored and modelled employing Airviro air quality dispersion modelling system in Sheffield, United Kingdom. The aim is to determine the most significant emission sources and their spatial variability. NOx emissions (ton/year) from road traffic, point and area sources for the year 2017 were 5370, 6774, and 2425, whereas those of PM10 (ton/year) were 345, 1449, and 281, respectively, which are part of the emission database. The results showed three hotspots of NOx, namely the Sheffield City Centre, Darnall and Tinsley Roundabout (M1 J34S). High PM10 concentrations were shown mainly between Sheffield Forgemasters International (a heavy engineering steel company) and Meadowhall Shopping Centre. Several emission scenarios were tested, which showed that NOx concentrations were mainly controlled by road traffic, whereas PM10 concentrations were controlled by point sources. Spatiotemporal variability and public exposure to air pollution were analysed. NOx concentration was greater than 52 µg/m3 in about 8 km2 area, where more than 66 thousand people lived. Models validated by observations can be used to fill in spatiotemporal gaps in measured data. The approach used presents spatiotemporal situation awareness maps that could be used for decision making and improving the urban infrastructure.

No abstract

High-resolution mass spectrometers generate large data files that are complex, noisy and require extensive processing to extract the optimal data from raw spectra. This processing is readily achieved in software and is often embedded in manufacturers' instrument control and data processing environments. However, the speed of this data processing is such that it is usually performed off-line, post data acquisition. We have been exploring strategies that would allow real-time advanced processing of mass spectrometric data, making use of the reconfigurable computing paradigm, which exploits the flexibility and versatility of Field Programmable Gate Arrays (FPGAs). This approach has emerged as a powerful solution for speeding up time-critical algorithms. We describe here a reconfigurable computing solution for processing raw mass spectrometric data generated by MALDI-ToF instruments. The hardware-implemented algorithms for de-noising, baseline correction, peak identification and deisotoping, running on a Xilinx Virtex 2 FPGA at 180 MHz, generate a mass fingerprint over 100 times faster than an equivalent algorithm written in C, running on a Dual 3 GHz Xeon workstation.

Land Use Regression (LUR) based on multiple linear regression model is one of the techniques used most frequently for modelling the spatial variability of air pollution and assessing exposure in urban areas. In this paper, a nonlinear generalised additive model is proposed for LUR and its performance is compared to a linear model in Sheffield, UK for the year 2019. Pollution models were estimated using NO2 measurements obtained from 188 diffusion tubes and 40 low-cost sensors. Performance of the models was assessed by calculating several statistical metrics including correlation coefficient (R) and root mean square error (RMSE). High resolution (100 m × 100 m) maps demonstrated higher levels of NO2 in the city centre, eastern side of the city and on major roads. The results showed that the nonlinear model outperformed the linear counterpart and that the model estimated using NO2 data from diffusion tubes outperformed the models using data from low-cost sensors or both low-cost sensors and diffusion tubes. The proposed method provides a basis for further application of advanced nonlinear modelling approaches to constructing LUR models in urban areas which enable quantifying small scale variability in pollution levels.

Small-scale spatial variability in NO2 concentrations is analysed with the help of pollution maps. Maps of NO2 estimated by the Airviro dispersion model and land use regression (LUR) model are fused with measured NO2 concentrations from low-cost sensors (LCS), reference sensors and diffusion tubes. In this study, geostatistical universal kriging was employed for fusing (integrating) model estimations with measured NO2 concentrations. The results showed that the data fusion approach was capable of estimating realistic NO2 concentration maps that inherited spatial patterns of the pollutant from the model estimations and adjusted the modelled values using the measured concentrations. Maps produced by the fusion of NO2-LCS with NO2-LUR produced better results, with r-value 0.96 and RMSE 9.09. Data fusion adds value to both measured and estimated concentrations: the measured data are improved by predicting spatiotemporal gaps, whereas the modelled data are improved by constraining them with observed data. Hotspots of NO2 were shown in the city centre, eastern parts of the city towards the motorway (M1) and on some major roads. Air quality standards were exceeded at several locations in Sheffield, where annual mean NO2 levels were higher than 40 µg/m3. Road traffic was considered to be the dominant emission source of NO2 in Sheffield.