An einem Metallatom oder am Phthalocyanin(pc)‐ Liganden findet die erste Oxidation der heteronuclearen Tripeldeckerkomplexe vom Typ 1 statt, je nachdem ob sie ein oxidierbares CeIII‐Ion enthalten oder nicht. Mit 1, M = Ce, M' = Gd, p = oep, gibt es nun auch den ersten röntgenographisch charakterisierten derartigen heteronuclearen Tripeldecker‐ komplex.
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