A two-stage,
inclined continuous rotary torrefier with novel flights
has been developed in the Biomass Conversion Laboratory at Dalhousie
University for improving biomass torrefaction processes. Experimental
work on torrefaction of small poplar wood particles (0.5–1.0
mm) in the torrefier was undertaken for a deeper understanding of
the working of such torrefiers where the volatile gas released was
used as the torrefaction medium instead of nitrogen. The rotary torrefier
is operated under different operating conditions by varying its rotational
speed, tilt angle and temperature. Measured chemical and physical
properties of the torrefied products included ultimate and proximate
analysis, structural analysis, energy density, mass yield, energy
yield, and bulk density. A novel probe was developed to collect samples
of biomass and measure temperature at different interior points along
the length of the rotary torrefaction reactor while the biomass was
being progressively torrefied in it. Axial temperature distribution
of the rotary torrefier showed a parabolic profile but the fixed carbon
content, volatile, and energy density of biomass undergoing torrefaction
varied linearly along the length of the torrefier. For torrefaction
at 300 °C and 5 rpm and 1° of tilt angle the change in heating
value was 40%, while the mass yield and energy yield of torrefied
biomass were 34% and 48%, respectively. Results showed that temperature
is the most important parameter in this torrefaction process.
A mechanistic model
of torrefaction was developed for a two-stage
rotary reactor, and it was verified with experimental results. Mass
and energy balances for each phase are considered in the model. A
kinetic model that considers the progressive decomposition of biomass
into volatiles and char released simultaneously from the raw biomass
was coupled to the balances. Mathematical expressions for residence
time, heat transfer coefficient, and bed height inside the kiln were
taken from the literature for model calculations. Release of condensable
and noncondensable volatiles from biomass during the process was considered
in the gas phase, while the solid phase included raw and torrefied
biomass. The model can predict different output parameters of torrefaction
in a rotary continuous torrefier, such as final amounts of solids,
gas yields, and temperatures, for different operational conditions.
Properties for torrefied solid, such as high heating value, fixed
carbon, and volatile matter, can also be predicted by the model through
mathematical correlations obtained in a previous experimental work.
The results obtained from the model were compared to experimental
data, and good agreement was found.
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