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International audienceThis research investigates the long-term shrinkage and Relative Mass Loss (RML) of mature Portland concretes (pure CEMI and blended CEMV/A), at temperatures of 20°C and 80°C. When placed at 80°C and at relative humidities (RH) below 50-60%, concrete shrinkage increases with very slow stabilization kinetics by several hundreds of μm/m, while RML remains of about 0.2%. The origins of this continued shrinkage, simultaneously with limited RML, are investigated through the changes in (i) the pore structure of the concretes (by Mercury Intrusion Porosimetry and nitrogen adsorption) and in (ii) their solid phases (by TGA/DTA, FTIR spectroscopy coupled to DVS, quantitative X-Ray Diffraction by Rietveld analysis, and 29Si and 27Al MAS NMR). While the pore structure coarsens during continued shrinkage, several phase transformations occur, namely ettringite decomposition and changes in the silicate chain length of the C–A–S–H. While these structural changes are documented, their relationship with shrinkage/RML and to the pore structure is novel

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