is an open access repository that collects the work of Arts et Métiers ParisTech researchers and makes it freely available over the web where possible. A B S T R A C TThis paper describes a hybrid additive manufacturing process -3D Laser Shock Peening (3D LSP), based on the integration of Laser Shock Peening (LSP) with selective laser melting (SLM). The well-known tensile residual stresses (TRS) in the as -built (AB) state of SLM parts in the subsurface region have a detrimental effect on their fatigue life. LSP is a relatively expensive surface post treatment method, known to generate deep CRS into the subsurface of the part, and used for high end applications (e.g. aerospace, nuclear) where fatigue life is crucial. The novel proposed 3D LSP process takes advantage of the possibility to repeatedly interrupt the part manufacturing, with cycles of a few SLM layers. This approach leads to higher and deeper CRS in the subsurface of the produced part, with expected improved fatigue properties. In this paper, 316L stainless steel samples were 3D LSP processed using a decoupled approach, i.e. by moving back and forth the baseplate from an SLM machine to an LSP station. A clear and significant increase in the magnitude and depth of CRS was observed, for all investigated process parameters, when compared to the AB SLM parts, or those traditionally LSP (surface) treated.

is an open access repository that collects the work of Arts et Métiers ParisTech researchers and makes it freely available over the web where possible. a b s t r a c tThe direct metal deposition (DMD) with laser is a free-form metal deposition process for manufacturing dense pieces, which allows generating a prototype or small series of near net-shape structures. One of the most critical issues is that produced pieces have a deleterious surface finish which systematically requires post machining steps. This problem has never been fully addressed before. The present work describes investigations on the DMD process, using an Yb-YAG disk laser, and a widely used titanium alloy (Ti-6Al-4V) to understand the influence of the main process parameters on the surface finish quality. The focus of our work was: (1) to understand the physical mechanisms responsible for deleterious surface finishes, (2) to propose different experimental solutions for improving surface finish.In order to understand the physical mechanisms responsible for deleterious surface finishes, we have carried out: (1) a precise characterization of the laser beam and the powder stream; (2) a large number of multi-layered walls using different process parameters (P(W), V(m/min), D m (g/min), Gaussian or uniform beam distribution); (3) a real time fast camera analysis of melt pool dynamics and melt-pool -powder stream coupling; (4) a characterization of wall morphologies versus process parameters using 2D and 3D profilometry.The results confirm that surface degradation depends on two distinct aspects: the sticking of nonmelted or partially melted particles on the free surfaces, and the formation of menisci with more or less pronounced curvature radii. Among other aspects, a reduction of layer thickness and an increase of melt-pool volumes to favor re-melting processes are shown to have a beneficial effect on roughness parameters. Last, a simple analytical model was proposed to correlate melt-pool geometries to resulting surface finishes.

The systematic occurrence of porosities inside selective laser melted (SLM) parts is a well-known phenomenon. In order to improve the density of SLM parts, it is important not only to assess the physical origin of the different types of porosities, but also to be able to measure as precisely as possible the porosity rate so that one may select the optimum manufacturing parameters. Considering 316 L steel parts built with different input energies, the current paper aims to (1) present the different types of porosities generated by SLM and their origins, (2) compare different methods for measuring parts density and (3) propose optimal procedures. After a preliminary optimization step, three methods were used for quantifying porosity rate: the Archimedes method, the helium pycnometry and micrographic observations. The Archimedes method shows that results depend on the nature and temperature of the fluid, but also on the sample volume and its surface roughness. During the micrographic observations, it has been shown that the results depend on the magnification used and the number of micrographs considered. A comparison of the three methods showed that the optimized Archimedes method and the helium pycnometry technique gave similar results, whereas optimized micrographic observations systematically underestimated the porosity rate. In a second step, samples were analyzed to illustrate the physical phenomena involved in the generation of porosities. It was confirmed that: (1) low Volume Energy Density (VED) causes non-spherical porosities due to insufficient fusion, (2) in intermediary VED the small amount of remaining blowhole porosities come from gas occlusion in the melt-pool and (3) in excessive VED, cavities are formed due to the keyhole welding mode.

a b s t r a c tThe effect of laser shock peening on the high temperature oxidation resistance of commercial pure titanium at high temperature (700°C) was studied in long-time (3000 h) exposure under dry air. A reduction of the gain mass by a factor 4 was found for laser-shock peened (LSP) samples compared to untreated titanium, which supports the interest of laser-shock treatment for the improvement of high temperature resistance. Short-durations (10 h and 100 h) oxidation experiments, devoted to investigate the influence of the LSP treatment on the first stages of the oxidation process, were also carried out by TGA. Several techniques as scanning electron microscopy, hardness and roughness measurements, X-ray diffraction and X-ray photoelectron spectrometry, microRaman spectroscopy, nuclear reaction analysis and electron backscattered diffraction were used to characterize the sample after laser treatment and oxidations. The formation of a continuous nitrogen-rich layer between the oxide layer and the α-case area in LSP samples appears to be the key factor to explain the reduction of oxygen diffusion, and thus the improvement of the oxidation resistance of laser shocked titanium. Moreover, the graintexture of LSP samples after oxidation can also explain the improvement of the high temperature oxidation resistance after long times exposures.

International audienceThe excellent combination of light-weight and good mechanical propertiesmakes titanium alloys attractive for compressor section components in gasturbine engines (temperature between 250 and 600 C). However, above 600 C,the formation of an unprotective oxide layer facilitates the oxygen diffusion into thealloy. In this experimental study, pure titanium was treated with mechanical surfacetreatment to promote better protection against oxidation at high temperature. Shotpeenedand laser-shock peened specimens were compared to untreated samples interms of oxidation behavior at high temperature. We used thermal gravimetricanalysis to oxidize the samples at 700 C for 100 h. Subsequently, XRD, opticalmicroscopy, SEM/EDS, NRA, micro-Raman spectroscopy, and micro-hardnesswere used to characterize the oxide scale and the alpha-case layer formed during thehigh-temperature exposure. The shot-peened samples oxidized less (-45%) than theuntreated and laser-shock peened samples. This behavior was attributed to theformation of a continuous nitride layer between oxide and meta

International audienceTitanium Matrix Composites (TMC's) containing various volume fractions of (TiB+TiC) particles have been deposited from powder feedstocks consisting of a blend of pre-alloyed (Ti-6Al-4V+B4C) powders, using the direct metal deposition (DMD) laser process and the in-situ chemical reaction 5Ti+B4C→4TiB+TiC. Process optimization has allowed to obtain a homogeneous distribution of tiny TiB whiskers within the Ti-6Al-4V α/β matrix, with a full solubilization of C for low B4C contents (0.5 wt% and 1.5 wt%), and the formation of a small amount of globular TiC particles at higher B4C content (3%). Comparisons with Ti-6Al-4V DMD walls revealed a substantial grain refinement on TMC's due to enhanced grain nucleation on TiB whiskers, even for low B4C contents. Last, mechanical investigations indicated an increase of 10–15% of Vickers hardness, and a constant 10% increase of Young modulus on a large temperature range (20–600 °C) for all B4C content

Improving the high temperature (HT) resistance of titanium alloys is currently a technological challenge for extending their use in aerospace engines. Ti-Beta-21S is a metastable β titanium alloy specifically designed for high temperature applications up to 593°C. We report the effect of a surface treatment by laser-shock peening (LSP) on the high temperature behavior of Ti-Beta-21S in order to increase further its maximum service temperature. The oxidation kinetics at 700°C for duration up to 3000 h showed that the LSP treatment increases the oxidation resistance of Ti-Beta-21S. The effects of the LSP treatment on the alloy microstructure, its evolution at high temperature and the diffusion of light atmospheric elements (oxygen and nitrogen) are also reported.

The Laser Metal Deposition (LMD) process is an additive manufacturing method, which generates 3D structures through the interaction of a laser beam and a gas/powder stream. The stream diameter, surface density and focal plan position affect the size, efficiency and regularity of the deposit tracks. Therefore, a precise knowledge of the gas/powder streams characteristics is essential to control the process and improve its reliability and reproducibly for industrial applications. This paper proposes multiple experimental techniques, such as gas pressure measurement, optical and weighting methods, to analyze the gas and particle velocity, the powder stream diameter, its focal plan position and density. This was carried out for three nozzle designs and multiple gas and powder flow rates conditions. The results reveal that (1) the particle stream follows a Gaussian distribution while the gas velocity field is closer to a top hat one; (2) axial, carrier and shaping gas flow significantly impact the powder stream’s focal plan position; (3) only shaping gas, powder flow rates and nozzle design impact the powder stream diameter. 2D axisymmetric models of the gas and powder streams with RANS turbulent model are then performed on each of the three nozzles and highlight good agreements with experimental results but an over-estimation of the gas velocity by pressure measurements.