Karst aquifers and watersheds represent a major source of drinking water around the world. They are also known as complex and often highly vulnerable hydrosystems due to strong surface-groundwater interactions. Improving the understanding of karst functioning is thus a major issue for the efficient management of karst groundwater resources. A comprehensive understanding of the various processes can be achieved only by studying karst systems across a wide range of spatiotemporal scales under different geological, geomorphological, climatic, and soil cover settings. The objective of the French Karst National Observatory Service (SNO KARST) is to supply the international scientific community with appropriate data and tools, with the ambition of (i) facilitating the collection of long-term observations of hydrogeochemical variables in karst, and (ii) promoting knowledge sharing and developing cross-disciplinary research on karst. This paper provides an overview of the monitoring sites and collective achievements, such as the KarstMod modular modeling platform and the PaPRIKa toolbox, of SNO KARST. It also presents the research questions addressed within the framework of this network, along with major research results regarding (i) the hydrological response of karst to climate and anthropogenic changes, (ii) the influence of karst on geochemical balance of watersheds in the critical zone, and (iii) the relationships between the structure and hydrological functioning of karst aquifers and watersheds.Abbreviations: CADI, cellular automata-based deterministic inversion; Ex/Em, excitation/emission; NOM, natural organic matter; SLP, sea level pressure; SNO Karst, the French Karst National Observatory Service.Karstified carbonate formations contain 25% of the world's water resources. They cover a very large extent of the continental surface: 10% of the global continental surface, 30 to 70% of the Mediterranean area, 22% of the land in Europe, and 50% in France (Chen et al., 2017). In carbonate karst hydrosystems, the presence of fractures, conduits, and surface solution features leads to strong surface-subsurface interactions that result in significant water, mass, energy, and contaminant transport within the critical zone. Such heterogeneous systems are highly dynamic, with complex hydrologic, geochemical, and biological processes occurring across a wide range of spatiotemporal scales. As a result, they Core Ideas • SNO KARST is dedicated to the study of karst functioning. • Hydrodynamics and geochemistry are measured at springs and in karst compartments. • Process sampling was set up at nine sites in various climatic contexts.

Abstract. The aim of this study is to present a framework that provides new ways to characterize the spatio-temporal variability of lateral exchanges for water flow and solute transport in a karst conduit network during flood events, treating both the diffusive wave equation and the advection–diffusion equation with the same mathematical approach, assuming uniform lateral flow and solute transport. A solution to the inverse problem for the advection–diffusion equations is then applied to data from two successive gauging stations to simulate flows and solute exchange dynamics after recharge. The study site is the karst conduit network of the Fourbanne aquifer in the French Jura Mountains, which includes two reaches characterizing the network from sinkhole to cave stream to the spring. The model is applied, after separation of the base from the flood components, on discharge and total dissolved solids (TDSs) in order to assess lateral flows and solute concentrations and compare them to help identify water origin. The results showed various lateral contributions in space – between the two reaches located in the unsaturated zone (R1), and in the zone that is both unsaturated and saturated (R2) – as well as in time, according to hydrological conditions. Globally, the two reaches show a distinct response to flood routing, with important lateral inflows on R1 and large outflows on R2. By combining these results with solute exchanges and the analysis of flood routing parameters distribution, we showed that lateral inflows on R1 are the addition of diffuse infiltration (observed whatever the hydrological conditions) and localized infiltration in the secondary conduit network (tributaries) in the unsaturated zone, except in extreme dry periods. On R2, despite inflows on the base component, lateral outflows are observed during floods. This pattern was attributed to the concept of reversal flows of conduit–matrix exchanges, inducing a complex water mixing effect in the saturated zone. From our results we build the functional scheme of the karst system. It demonstrates the impact of the saturated zone on matrix–conduit exchanges in this shallow phreatic aquifer and highlights the important role of the unsaturated zone on storage and transfer functions of the system.

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