Modeling approach for mesoscopic model of concrete depicting mass transportation and physicochemical reaction is important since there is growing demand for accuracy and computational efficiency of numerical simulation. Mesoscopic numerical simulation considering binder, aggregate, and interfacial transition zone (ITZ) generally produces huge number of DOFs, which is inapplicable for full structure. In this paper, a two-dimensional multiscale approach describing three-phase structure of concrete was discussed numerically. An effective approach generating random aggregate in polygon based on checking centroid distance and intersection of line segment was introduced. Moreover, ITZ elements were built by parallel expanding the edge of aggregates on inner side. By combining mesoscopic model including full-graded aggregate and macroscopic model, cases related to diffusivity and width of ITZ, volume fraction, and grade of aggregate were studied regarding the consideration of multiscale compensation. Result clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Finally, this paper addressed some noteworthy conclusions about the chloride distribution and rebar corrosion regarding the configuration of rebar diameter, concrete cover, and exposure period.
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