The Walker Top Granite (here formally named) is a peraluminous megacrystic granite that occurs in the Cat Square terrane, Inner Piedmont, part of the southern Appalachian Acadian-Neoacadian deformational and metamorphic core. The granite occurs as disconnected concordant to semi-concordant plutons in migmatitic, sillimanite zone rocks of the Brindle Creek thrust sheet. Locally garnet-bearing, the Walker Top Granite contains blocky alkali feldspar megacrysts 1–10 cm long in a groundmass of muscovite-biotite-quartz-plagioclase-alkali feldspar and accessory to trace zircon, titanite, epidote, sillimanite (xenocrysts), and apatite. It varies from granite to granodiorite and contains several xenoliths of biotite gneiss, amphibolite, quartzite, and in one location encloses charnockite (here formally named Vale Charnockite). New sensitive high-resolution ion microprobe U-Pb zircon magmatic crystallization ages obtained from the plutons of the Walker Top Granite are: 407 ± 1 Ma in the Brushy Mountains; 366 ± 2 Ma in the South Mountains; and 358 ± 5 Ma in the Vale–Cat Square area. An age of 366 ± 3 Ma was obtained from the Vale Charnockite at its type locality. Major-, trace-element, and isotopic chemistry indicates that Walker Top is a high-K, peraluminous granite, plotting as volcanic arc or syn-collisional on tectonic discrimination diagrams and suggests that it represents deep-seated anatectic magma with S- to I-type affinity. The alkali calcic, ferroan Vale Charnockite likely formed by deep crustal melting, and similar geochemical and trace-element compositions suggest a similar tectonic origin as Walker Top Granite. The discontinuous nature of the Walker Top Granite plutons precludes it intruded as a volcanic arc. Instead, the peraluminous nature, common xenoliths of surrounding country rock, and geochemical and isotopic signatures suggest it formed by partial melting of Cat Square and Tugaloo terrane rocks. Following emplacement and crystallization, Walker Top plutons were deformed into elliptical to linear shapes—SW-directed sheath folds—enveloped by partially melted, pelitic and quartzofeldspathic rocks. Collectively, Walker Top and other plutons helped weaken the crust and facilitate lateral crustal flow in a SW-directed, tectonically driven orogenic channel during the Acadian-Neoacadian event. A comparison with the northern Appalachians recognizes a similar temporal magmatic and deformational history during the Acadian and Neoacadian orogenies, although while the Walker Top Granite intruded the lower plate during eastward subduction beneath the peri-Gondwanan Carolina superterrane, the northern Appalachian plutons intruded the upper plate during subduction of the Avalon superterrane westward beneath Laurentia. We hypothesize that a transform fault, located near the southern end of the New York promontory, accommodated oppositely directed lateral plate motion and different subduction polarity between the Carolina and Avalon superterranes during the Acadian and Neoacadian orogenies.
Manganese oxide deposits have long been observed in association with carbonates within the Appalachian Mountains, but their origin has remained enigmatic for well over a century. Ore deposits of Mn oxides from several productive sites located in eastern Tennessee and northern Virginia display morphologies that include botryoidal and branching forms, massive nodules, breccia matrix cements, and fracture fills. The primary ore minerals include hollandite, cryptomelane, and romanèchite. Samples of Mn oxides from multiple localities in these regions were analyzed using electron microscopy, X-ray analysis, Fourier transform infrared spectroscopy, and trace/rare earth element geochemistry. The samples from eastern Tennessee have biological morphologies, contain residual biopolymers, and exhibit REE signatures that suggest the ore formation was due to supergene enrichment (likely coupled with microbial activity). In contrast, several northern Virginia ores hosted within quartz-sandstone breccias exhibit petrographic relations, mineral morphologies, and REE signatures indicating inorganic precipitation, and a likely hydrothermal origin with supergene overprinting. Nodular accumulations of Mn oxides within weathered alluvial deposits that occur near to breccia-hosted Mn deposits in Virginia show geochemical signatures that are distinct from the breccia matrices, and appear to reflect remobilization of earlier-emplaced Mn and concentration within supergene traps. Based on the proximity of all of the productive ore deposits to mapped faults or other zones of deformation, we suggest that the primary source of all of the Mn may have been deep-seated, and that Mn oxides with supergene and/or biological characteristics result from the local remobilization and concentration of this primary Mn. Carmichael ABSTRACTManganese oxide deposits have long been observed in association with carbonates within the Appalachian Mountains, but their origin has remained enigmatic for well over a century. Ore deposits of Mn oxides from several productive sites located in eastern Tennessee and northern Virginia display morphologies that include botryoidal and branching forms, massive nodules, breccia matrix cements, and fracture fills. The primary ore minerals include hollandite, cryptomelane, and romanèchite. Samples of Mn oxides from multiple localities in these regions were analyzed using electron microscopy, X-ray analysis, Fourier transform infrared spectroscopy, and trace/rare earth element geochemistry. The samples from eastern Tennessee have biological morphologies, contain residual biopolymers, and exhibit REE signatures that suggest the ore formation was due to supergene enrichment (likely coupled with microbial activity). In contrast, several northern Virginia ores hosted within quartz-sandstone breccias exhibit petrographic relations, mineral morphologies, and REE signatures indicating inorganic precipitation, and a likely hydrothermal origin with supergene overprinting. Nodular accumulations of Mn oxides within weathered al...
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