Measured activation parameters, as well as the effect on rate of adding inert electrolytes, are consistent with solvolysis of p‐(dimethylamino)benzenesulfonyl chloride XI occurring through a concerted, asynchronous bimolecular mechanism, in which bond breaking takes place far ahead of bond formation in the transition state.
Die Titelverbindung (I) reagiert als Dienophil mit den in Position 1 substituierten 1,3‐Butadienen (II) und mit den in Position 2 substituierten Butadienen (IV) in einer Diels‐Alder‐Reaktion zu den 1,2‐Thiazinoxiden (III) bzw. (V), die als o‐Addukte bzw. p‐Addukte klassifiziert werden.
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