Hydrolysis is the most critical stage in high solids Temperature Phased Anaerobic Digestion (TPAD). In this paper two different Organic Fraction of Municipal Solid Waste (OFMSW) types were tested in co-digestion with Digested Sludge (DS) at different temperatures: 37, 55 and 65 °C. Volatile fatty acids (VFAs), soluble chemical oxygen demand (CODs) and Biochemical Methane Production (BMP) were measured and calculated after 0, 24, 48 and 72 h hydrolysis. The results showed that both the BMP and the methane production rate improved. A Solids Retention Time (SRT) of 72 h at a temperature of 55°C gave the best results: the reaction rate constant k was 0.34 d -1 and the BMP was 250 mLCH4/gMV, which were 47% and 19% higher compared to the reference (0 h hydrolysis). The CODs and VFAs profiles during hydrolysis showed how OFMSW initial characteristics can affect the performance of temperature phased anaerobic digestion.
The objectives of this study were to: (1) quantify differences in biochemical methane potential (BMP) measured using three measurement methods, including two popular methods (a commercial automated system (AMPTS II) and manual manometric) and one newer method (gravimetric), and (2) assess the importance of the mixing position in the measurement sequence. Powdered microcrystalline cellulose was used as the substrate in simultaneous tests. All methods gave similar results (<8% difference in the mean BMP) and were reasonably accurate (recovery of 80–86% of the theoretical maximum BMP). Manometric BMP values were consistently lower than gravimetric by 4–5%. Precision was lower for the automated method (relative standard deviation (RSD) of about 7%) than for the manual methods (RSD about 1–3%). Mixing after biogas measurement resulted in 3% higher BMP for both manual methods than mixing before, due to the lower measured CH4 production from blanks. This effect may be linked to a fraction of CH4 that remains dissolved or even as attached bubbles, and suggests that mixing before measurement is preferable. The automated volumetric and gravimetric methods (mode 2) gave very similar mean BMP values (1% different). However, kinetic analysis showed that methane production was faster with the automated volumetric method. This could come from an error in the estimation of the CH4 production rate for the automated method, or an increase in the degradation rate due to better mixing. Both automatic volumetric and manual gravimetric measurements met current validation criteria for mean cellulose BMP, but the RSD from the automated system exceeded the limit.
In this study an experimental study on a biological methane oxidation column presented with the aim to calibrate a mathematical model developed in an earlier study. The column was designed to reproduce at lab-scale a real biofilter trying to consider the more probable landfill boundary conditions. Although the methane oxidation efficiency in the column was lower than the expected (around 35%), an appropriate model implementation showed an acceptable agreement between the outcomes data of the model simulation and the experimental data (with Theil's Inequality Coefficient value of 0.08). A calibrated model allows a better management of the biofilter performance in terms of methane oxidation.
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