The molecular sieve UTD-1 is investigated using scanning and
transmission electron microscopies (TEM),
solid-state NMR spectroscopy, electron (ED) and X-ray diffraction
(XRD), adsorption studies, and catalytic test
reactions. The results confirm that UTD-1 is the first high-silica
zeolite to contain a one-dimensional, extra-large
14-ring pore system. TEM and ED show that UTD-1 is faulted along
the (002) planes. Simulations of XRD patterns
of faulted structures using DIFFaX indicate that the XRD pattern of a
framework containing the so-called double
crankshaft chains is in better agreement with the experimental pattern
than a framework with the narsarsukite chains
previously reported. Thermal/hydrothermal stability studies show
that UTD-1 has similar stability to other medium-
and large-pore, high-silica zeolites. The ratio of isomerization
to disproportionation, and the distribution of
trimethylbenzene isomers in the m-xylene isomerization test
reaction from UTD-1 are similar to those obtained from
other large-pore zeolites (zeolites Y or L). However, UTD-1 shows
a p-/o-xylene ratio of products below
one.
Table 10. Anisotropic displacement parameters Ulj [107 pm 2 ] for la. The anisotropic displacement factor exponent takes the form:-2 it 2 [h 2 a* 2 U 1 1 + ... + 2 h k a* b* U 12 ].
A model for the structure of the zeolite SSZ-31 is presented.
The model is obtained by combining
information from adsorption capacity measurements, transmission
electron microscopy, and high-resolution X-ray
diffraction. SSZ-31 is a one-dimensional large-pore zeolite with a
framework density of 18.7 tetrahedral(T)-atoms
per nm-3 and a bulk density of 1.87 g
cm-3. The pore apertures are elliptical
with major and minor axes of
approximately 8.6 Å × 5.7 Å. SSZ-31 is an extreme example of a
complex and highly faulted zeolite. The structure
can be described as an intergrowth of four different but structurally
related polymorphs.
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