SARS-CoV-2 is shed by COVID-19 patients and can be detected in wastewater. Thus, testing wastewater for the virus provides a depiction of disease prevalence in a community. Virus concentration data can be utilized to monitor infection trends, identify hot spots, and inform decision makers regarding reopening efforts and directing resources. This perspective aims to shed light on the current situation relating to SARS-CoV-2 in the wastewater system and the opportunity to utilize wastewater to collect useful epidemiological data. First, the survivability of SARS-CoV-2 in different water matrices is examined through the lens of surrogate viruses. Second, the effect of wastewater treatment processes on SARS-CoV-2 is investigated. Current standards for sufficient reduction of the virus and the risk of exposure that arises at each stage in the wastewater treatment process are discussed. Third, the immense potential of wastewater-based epidemiology (WBE) for managing the ongoing COVID-19 pandemic is analyzed. Studies that have tested wastewater or sludge for SARS-CoV-2 are discussed, and results are tabulated. Lastly, the current limitations of WBE and opportunities of future research are explored. Using the wealth of knowledge that the scientific community now has about WBE, wastewater testing should be considered by regional governments and private institutions.
Hybrid ceramic−polymer solid state electrolytes are promising candidates to enable energy-dense lithium metal batteries by leveraging inorganic high ionic conductivity and flexible polymer mechanical properties. However, studies of hybrid electrolytes using sulfide-type inorganics such as Li 3 PS 4 (LPS) have largely focused on combining the inorganic with commercial poly(ethylene oxide) (PEO). PEO has proven to be insufficient for use in hybrid systems because it reacts with LPS and provides a competing pathway for ion transport, therefore producing a hybrid with low conductivity. Our work shows that using nonconductive, nonpolar polyethylene (PE) in hybrid electrolytes with LPS eliminates both polymer and inorganic degradation and remarkably, exhibits higher conductivities than those containing PEO at different polymer and salt concentrations. Using tracerexchange NMR, we observe that the nonconductive nature of PE allows for ion transport through the inorganic whereas PEO provides a separate, competing pathway for lithium transport. Furthermore, compared to pure LPS, these hybrids enable longer term lithium cycling at 60 °C. Our work shows that the path to enabling conductive and stable sulfide hybrids for solid state lithium-metal batteries may be through the use of nonconductive, nonreactive polymers.
Microplastics (MPs) are tiny pieces of plastic (<5 mm) that have been manufactured, shed from textiles, or formed as the degradation products of macroplastics. They can be taken up by aquatic organisms, leading to their incorporation into the food chain. Humans can consume MPs from fish as well as other impacted sources including bottled and tap water. MPs may pose risks to exposed organisms, and they can also act as vectors carrying additional adsorbed chemical pollutants and pathogens. MPs are an especially important focus regarding the Great Lakes because plastics comprise most of the litter, and the Great Lakes serve as a source of drinking water for 40 million people. This perspective summarizes the current state of MP pollution in the Great Lakes and potential risks posed to the environment, wildlife, and humans. A survey of detection, separation, and quantification methods is included. Potential remedies are explored, focusing on policy, human behavior, and the goal of a circular economy. Further research directions include standardizing detection and removal methods, assessing the health risk of MPs in the Great Lakes, and evaluating mitigation options.
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