Cocrystal engineering is an advanced supramolecular strategy that has attracted a lot of research interest. Many studies on cocrystals in various application fields have been reported, with a particular focus on the optoelectronics field. However, few articles have combined and summarized the electronic and magnetic properties of cocrystals. In this review, we first introduce the growth methods that serve as the basis for realizing the different properties of cocrystals. Thereafter, we present an overview of cocrystal applications in electronic and magnetic fields. Some functional devices based on cocrystals are also introduced. We hope that this review will provide researchers with a more comprehensive understanding of the latest progress and prospects of cocrystals in electronic and magnetic fields.
Simultaneously realizing the optical and electrical properties of organic materials is always challenging. Herein, a convenient and promising strategy for designing organic materials with integrated optoelectronic properties based on cocrystal engineering has been put forward. By selecting the fluorene (Flu) and the 7,7′,8,8′-tetracyanoquinodimethane (TCNQ) as functional constituents, the Flu-TCNQ cocrystal prepared shows deep red emission at 702 nm, which is comparable to the commercialized red quantum dot. The highest electron mobility of organic field-effect transistor (OFET) based on Flu-TCNQ is 0.32 cm2 V−1 s−1. Spectroscopic analysis indicates that the intermolecular driving force contributing to the co-assembly of Flu-TCNQ is mainly charge transfer (CT) interaction, which leads to its different optoelectronic properties from constituents.
Graphical Abstract
Organic cocrystal strategy provides a shortcut toward ambipolar materials, but remains challenge in realizing excellent electrical performance due to the lack of definite direction in rational design of cocrystal. Herein,...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.