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In this work, highly efficient Cu x −Mn composite catalysts (0 ≤ x ≤ 0.20) were synthesized by an improved hydrothermal−citrate complex method and tested in the catalytic total oxidation of CO and the removal of NO by CO. The influence of Cu on manganese oxide materials was characterized by several techniques, including FESEM, HRTEM, XRD, BET analysis, H 2 TPR, O 2 TPD, XPS, and DRIFTS. Possible reaction mechanisms for the NO + CO model reaction and CO oxidation were also tentatively proposed. The Cu-modified manganese oxide materials showed higher catalytic activity in CO oxidation and the selective catalytic reduction (SCR) of NO with CO than pure MnO x materials. The improved catalytic activity in CO oxidation observed for the copper−manganese oxide catalyst was associated with a greater amount of adsorbed oxygen species and high lattice oxygen mobility due to the formation of a Cu 1.5 Mn 1.5 O 4 spinel active phase (CuFurthermore, in terms of the CO-SCR model reaction, the surface-dispersed Cu x+ −O 2− −Mn y+ active species could be reduced to a Cu + −□−Mn (4−x)+ active species, which was considered to be the primary active component in the reduction of NO by CO. The results of the catalytic performance testing indicated that Cu 0.075 Mn had the highest catalytic activity in CO oxidation, whereas Cu 0.15 Mn exhibited the best CO-SCR catalytic performance.

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Overgeneration of reactive oxygen species (ROS) is closely associated with cellular damage and diseases. As superoxide anion (O2(•-)) is the precursor of other ROS, exploring O2(•-) fluctuations in cells and in vivo is of great significance. To address this critical need, we have developed a novel reversible fluorescent probe with one-photon and two-photon fluorescence properties, which is well suited for monitoring O2(•-) fluxes selectively and dynamically. Imaging results substantiate dynamic and reversible fluorescence responses of this probe to intracellular O2(•-) under apoptotic stimuli. Moreover, this probe can conveniently visualize changes in O2(•-) concentration during reperfusion injury in hepatocytes, zebrafish, and mice, by means of one-photon or two-photon imaging according to depths of various samples. The present study provides a powerful fluorescent imaging tool for dynamic tracking of O2(•-) in live cells and in vivo.

In this work, ultra-small Cu(2)O nanoparticles have been loaded on TiO(2) nanosheets with {001} facets exposed through a one-pot hydrothermal reaction. These Cu(2)O nanoparticles are well-dispersed on TiO(2) nanosheets with narrow size distributions and controllable sizes from 1.5 to 3.0 nm. Through XRD, TEM, N(2) absorption-desorption isotherms and UV-vis diffuse reflectance spectra, the Cu(2)O/TiO(2) nanosheets show similar phase structures, morphologies, pore structures as compared to pure TiO(2) nanosheets. Due to the loading of ultra-small Cu(2)O nanoparticles, heterojunctions are formed between Cu(2)O and TiO(2), which favors the efficient separation of photo-generated electrons and holes. Caused by the electron transfer from Cu(2)O to TiO(2), Cu(2)O/TiO(2) nanosheets show excellent visible-light activity, about 3 times that of N-doped TiO(2) nanosheets with {001} facets exposed. Furthermore, charge transfer rate across the interface of Cu(2)O and TiO(2) shows great dependence on the size of Cu(2)O particles. The charge transfer across the interface may be more efficient between TiO(2) nanosheets and smaller Cu(2)O nanoparticles. Therefore, the Ti : Cu = 30 : 1(atomic ratio) sample shows the best activity due to its balance in light harvest and electron transfer rate in the degradation of phenol under visible light.

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