No abstract

The ability to remotely control pressure in diamond anvil cells (DACs) in accurate and consistent manner at room temperature, as well as at cryogenic and elevated temperatures, is crucial for effective and reliable operation of a high-pressure synchrotron facility such as High Pressure Collaborative Access Team (HPCAT). Over the last several years, a considerable effort has been made to develop instrumentation for remote and automated pressure control in DACs during synchrotron experiments. We have designed and implemented an array of modular pneumatic (double-diaphragm), mechanical (gearboxes), and piezoelectric devices and their combinations for controlling pressure and compression/decompression rate at various temperature conditions from 4 K in cryostats to several thousand Kelvin in laser-heated DACs. Because HPCAT is a user facility and diamond cells for user experiments are typically provided by users, our development effort has been focused on creating different loading mechanisms and frames for a variety of existing and commonly used diamond cells rather than designing specialized or dedicated diamond cells with various drives. In this paper, we review the available instrumentation for remote static and dynamic pressure control in DACs and show some examples of their applications to high pressure research.

The FORMOSA Satellite Series No. 3/Constellation Observing System for Meteorology, Ionosphere and Climate (FORMOSAT-3/COSMIC) spacecraft constellation consisting of six low-earth-orbiting satellites is the world's first operational Global Positioning System (GPS) radio occultation mission. The mission has been jointly developed by the National Space Organization of Taiwan and the University Corporation for Atmospheric Research of the U.S. in collaboration with the Jet Propulsion Laboratory, NASA, and the Naval Research Laboratory for three onboard payloads, including a GPS Occultation Receiver, a triband beacon, and a tiny ionospheric photometer. The FORMOSAT-3/COSMIC mission was successfully launched from Vandenberg into the same orbit plane of the designated 516-km circular parking orbit altitude on April 15, 2006. After the six satellites completed the in-orbit checkout activities, the mission was started immediately at the parking orbit for in-orbit checkout, calibration, and experiment of three onboard payloads. Individual spacecraft thrust burns for orbit raising were performed to begin the constellation deployment of the satellites into six separate orbit planes. All six FORMOSAT-3/COSMIC satellites are maintained in a good state of health except spacecraft flight model no. 2, which has had power shortages. Five out of the six satellites had reached their final mission orbits of 800 km as of November 2007. This paper provides an overview of the constellation spacecraft design, constellation mission operations, constellation deployment timeline evolution, associated spacecraft mass property and moment of inertia results, orbit-raising challenges, and lessons learned during the orbit-raising operations.

The structural phase transitions in Sm2O3 with mixed phases of cubic and monoclinic as starting material were studied by in situ high-pressure synchrotron angle dispersive x-ray diffraction and Raman scattering measurements up to 40.1 GPa and 41.0 GPa, respectively. The x-ray diffraction data indicate that the monoclinic and cubic phases begin to transform to a hexagonal phase at 2.5 and 4.2 GPa, respectively. The hexagonal phase is stable up to at least 40.1 GPa and could not be quenched to ambient conditions. These phase transitions have also been confirmed by Raman spectroscopy. A third-order Birch-Murnaghan fit based on the observed pressure-volume data yields zero pressure bulk moduli B0 = 149(2), 153(7), and 155(5) GPa for cubic, monoclinic, and hexagonal phases, respectively, when their first pressure derivatives (B0′) were fixed as 4. The pressure coefficients of Raman peaks and the mode Grüneisen parameters of different Raman modes were also obtained. Coupled with previous results, we conclude that the transition pressure of medium rare-earth sesquioxides from the cubic and monoclinic to the hexagonal phase increase with the decreasing of the cation radius.