Lithium (Li) metal is one of the most promising anode candidates for next‐generation rechargeable batteries with a high energy density because of its high theoretical specific capacity and low reduction potential. However, the growth of lithium dendrites causes intolerable safety risks and poor electrochemical performances. Limiting the migration of anions near the Li‐metal anode is regarded as an effective strategy to achieve uniform Li deposition and thus suppress the dendritic growth. Here, a metal‐organic frameworks based polyvinylidene fluoride‐hexafluoropropylene copolymer composite interlayer is designed and prepared through an in situ heat‐assisted method. Being guided and assisted by the anion‐shielded composite interlayer, a homogenous Li‐ion flux as well as a high Li‐ion transference number are achieved, which promotes the uniform and stable lithium deposition. At the same time, the robust composite interlayer is expected to suppress the growth of Li dendrites by its intrinsically high modulus (≈2.49 GPa). As a result, symmetrical batteries exhibit excellent cyclic stability for over 1600 h with functional composite interlayer. Furthermore, full cells with a commercial lithium iron phosphate cathode demonstrate remarkably enhanced cycling performance with a satisfying capacity retention of 96 % after 500 cycles. This work provides an effective strategy for the design and fabrication of functional composite interlayers to realize stable lithium metal anodes.
In this paper, the method of model established on reinforced concrete pier based on OpenSees was studied, and the parameter sensitivity analysis to OpenSees was carried out according to the test data. On the basis of introducing the related material model and element type, how to determine material model and element division as well as section meshing were studied, and the method of model established both reasonable and effective was given. The model of concrete material which can improve the convergence of calculation and the model of reinforced materials which can simulate elastic and reinforced plastic stage accurately were given in this paper. The results show that the distributed plastic beam-column element based on displacement can get higher calculation precision. At the same time, the bridge pier structure should be meshed sufficient number of elements and girds to meet the requirement of calculated accuracy.
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