Optical to electrical power converting semiconductor devices were achieved with breakthrough performance by designing a Vertical Epitaxial Heterostructure Architecture. The devices are featuring modeled and measured conversion efficiencies greater than 65%. The ultrahigh conversion efficiencies were obtained by monolithically integrating several thin GaAs photovoltaic junctions tailored with submicron absorption thicknesses and grown in a single crystal by epitaxy. The heterostructures that were engineered with a number N of such ultrathin junctions yielded an optimal external quantum efficiencies approaching 100%/N. The heterostructures are capable of output voltages that are multiple times larger than the corresponding photovoltage of the input light. The individual nanoscale junctions are each generating up to ∼1.2 V of output voltage when illuminated in the infrared. We compare the optoelectronic properties of phototransducers prepared with designs having 5 to 12 junctions and that are exhibiting voltage outputs between >5 V and >14 V.
An overview is presented of recently developed light‐mediated methods for ferroelectric domain engineering of lithium niobate single crystals. These methods include light‐assisted poling, UV laser‐induced inhibition of poling, and all‐optical poling. In addition to the primary application of ferroelectric domain patterns, namely the realization of non‐linear optical devices, the ability of transferring a domain pattern into a topographical structure by domain selective etching allows also for surface structuring of lithium niobate. This intertwining between ferroelectric domain patterns and surface topography has been used to fabricate exquisite micro‐structures based on unusual domains generated purposefully by these light‐mediated methods.
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