The effect of X-ray and low-energy (50 eV) electron irradiation on short-chain alkanethiolate (AT) selfassembled monolayers (SAMs) on Au(111) was studied by synchrotron-based high resolution X-ray photoelectron spectroscopy and infrared reflection absorption spectroscopy. As a test system, a SAM of hexanethiolate (C6) was used, whereas an analogous long-chain film, dodecanethiolate (C12) SAM, was taken as a reference. While both the C6 and C12 films exhibited a full range of irradiation-induced reactions characteristic of AT SAMs on coinage metal substrates, the branching of the reactions in these two systems was distinctly different. Whereas in the case of C12/Au, the dominant processes were decomposition of the alkyl chains and capture of the released alkylsulfide moieties in the aliphatic matrix, desorption of the complete molecular species emerging after the cleavage of the thiolate-gold bond prevailed in the case of C6/Au. This behavior was explained by higher volatility of the released C6 species and the reduced chemical activity of the alkyl matrix in C6/Au as compared to C12/Au. This matrix contained far less active sites than C12/Au due to enhanced quenching of the primary dissociative excitations by the dipole-image dipole interaction with the substrate. The efficiency of this distance-dependent process is especially high for short-chain AT SAMs.
We have prepared a thermally activated delayed fluorescence (TADF) capable molecular system carrying halogen substituents at the carbazole units. The attachment of the halogen atoms considerably decreases the half-life of the delayed fluorescence. The effect is significant. The heavier the halogen, the greater the effect. Our materials have the shortest reported emissive lifetimes for TADF achieved to date. Intersystem crossing (ISC) is improved through the heavy atom effect, yet high quantum yields are achieved both in solution as well as in thin doped films. The simple and efficient synthesis of our targets uses inexpensive and easily obtained starting materials.
We describe the efficient synthesis of substituted benzo[3,4]cyclobuta[1,2-b]phenazine, benzo[3,4]cyclobuta[1,2]benzo[1,2-i]phenazine, and benzo[3,4]cyclobuta[1,2-b]naphtho[2,3-i]phenazine by a condensation reaction of aromatic diamines with the stable biphenylene-2,3-dione.
We demonstrate that aldehyde-substituted donor-acceptor cruciforms [1,4-bis(arylethynyl)-2,5-distyrylbenzenes] are useful dosimeters for primary amines, primary diamines, and secondary amines. The 1,n-diamines are particularly reactive towards this dosimeter and can be detected in less than 100 ppm concentration. Using a single aldehyde-functionalized cruciform in seven different solvents allowed us to discern fourteen different amines by digital photography and statistical evaluation of the response patterns extracted as red, green, blue (RGB) values.
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