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Keywords: Kinetics / Linear free energy relationships / Carbocations / SolvolysisIonization rate constants of differently substituted trityl halides and carboxylates have been determined by conductimetry at 25°C in aqueous acetonitrile and in acetone. Common ion return was suppressed by the addition of piperidine, which traps the generated tritylium ions. The obtained rate constants were subjected to Winstein-Grunwald and Hammett analyses. The solvolysis rate constants of trityl chlorides

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