The reaction muscovite+cordierite→biotite+Al2SiO5 +quartz+H2O is of considerable importance in the low pressure metamorphism of pelitic rocks: (1) its operation is implied in the widespread assemblage Ms + Crd +And± Sil + Bt + Qtz, a common mineral assemblage in contact aureoles and low pressure regional terranes; (2) it is potentially an important equilibrium for pressure estimation in low pressure assemblages lacking garnet; and (3) it has been used to distinguish between clockwise and anticlockwise P–T paths in low pressure metamorphic settings. Experiments and thermodynamic databases provide conflicting constraints on the slope and position of the reaction, with most thermodynamic databases predicting a positive slope for the reaction. Evidence from mineral assemblages and microtextures from a large number of natural prograde sequences, in particular contact aureoles, is most consistent with a negative slope (andalusite and/or sillimanite occurs upgrade of, and may show evidence for replacement of, cordierite). Mineral compositional trends as a function of grade are variable but taken as a whole are more consistent with a negative slope than a positive slope. Thermodynamic modelling of reaction and associated equilibria results in a low pressure metapelitic petrogenetic grid in the system K2O–FeO–MgO–Al2O3–SiO2–H2O (KFMASH) which satisfies most of the natural and experimental constraints. Contouring of the Fe–Mg divariant interval represented by reaction allows for pressure estimation in garnet‐absent andalusite+cordierite‐bearing schists and hornfelses. The revised topology of reaction allows for improved analysis of P–T paths from mineral assemblage sequences and microtextures in the same rocks.

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Contact metamorphism of greenschist facies Neoproterozoic turbidites by the Cretaceous Bugaboo Batholith in southeastern British Columbia has resulted in a well‐developed contact aureole. The aureole is about 1 km wide and can be divided into three main zones: (i) spotted phyllite zone, extending from the first appearance of spots of cordierite or andalusite to the last occurrence of primary chlorite; (ii) cordierite + andalusite + biotite zone, comprising hornfelses or schists with abundant porphyroblasts of cordierite and andalusite and, at higher grades, fibrolitic sillimanite; and (iii) K‐feldspar zone, characterized by hornfelses and schists that, in the inner part of this zone, are variably migmatitic. Four parts of the aureole were examined, three of which are characterized by schists, and one of which (Cobalt Lake area) is characterized by hornfelses and has exceptional exposure and comparatively unaltered rocks. Petrographic, modal, mineral‐compositional and whole rock‐compositional data were collected from the Cobalt Lake transect, allowing the prograde reaction sequence to be inferred. Notable features of the aureole at Cobalt Lake include: initial development of andalusite and plagioclase at the expense of paragonite‐rich white mica; a narrow interval across which cordierite, andalusite and biotite increase markedly at the expense of chlorite; gradual development of andalusite and biotite at the expense of cordierite and muscovite upgrade of chlorite consumption; and near‐simultaneous development of andalusite + K‐feldspar and sillimanite, the latter indicating a pressure of contact metamorphism of ~3 kbar. In other parts of the aureole, the development of sillimanite downgrade of the initial development of K‐feldspar suggests slightly higher pressures of contact metamorphism. Lack of correspondence between the observed sequence of reactions in the aureole and those predicted thermodynamically suggests that modifications to some of the thermodynamic data or activity–composition models may be required. Textural features in the aureole suggest the influence of kinetic factors on metamorphic recrystallization, including: (i) deformation‐catalysed reaction in the schists compared to the hornfelses, as indicated by different mineral‐growth sequences inferred from microstructures, and (ii) heating rate‐controlled recrystallization, as indicated by the decrease in grain size of hornfelses with increasing metamorphic grade.

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