Based on a porous carbon electrode, capacitive deionization (CDI) is a promising desalination technology in which ions are harvested and stored in an electrical double layer.
The demand for lithium has greatly increased with the rapid development of rechargeable batteries. Currently, the main lithium resource is brine lakes, but the conventional lithium recovery process is time consuming, inefficient, and environmentally harmful. Rechargeable batteries have been recently used for lithium recovery, and consist of lithium iron phosphate as a cathode. These batteries feature promising selectivity between lithium and sodium, but they suffer from severe interference from coexisting magnesium ions, an essential component of brine, which has prompted further study. This study reports on a highly selective and energy-efficient lithium recovery system using a rechargeable battery that consists of a λ-MnO2 positive electrode and a chloride-capturing negative electrode. This system can be used to recover lithium from brine even in the presence of magnesium ions as well as other dissolved cations. In addition, lithium recovery from simulated brine is successfully demonstrated, consuming 1.0 W h per 1 mole of lithium recovered, using water similar to that from the artificial brine, which contains various cations (mole ratio: Na/Li ≈ 15.7, K/Li ≈ 2.2, Mg/Li ≈ 1.9).
This work introduces for the first time titanium disulfide (TiS 2 )/carbon nanotube (CNT) electrodes for desalination of high molarity saline water. Capitalizing on the two-dimensional layered structure of TiS 2 , cations can be effectively removed from a feedwater stream by intercalation. The TiS 2 −CNT hybrid electrode is paired in an asymmetric cell with microporous activated carbon cloth without an ion exchange membrane. By electrochemical analysis, the correlation between the state of charge and the stability of TiS 2 was investigated. By using post-mortem X-ray diffraction, the sodium-ion intercalation mechanism gives an insight into how the state of charge affects the structure and cyclic stability. Our system showed stable desalination performance over 70 cycles at high molar concentration (600 mM), with a cell salt removal capacity of 14 mg/g (equivalent to a sodium removal capacity of 35.8 mg/g normalized to the mass of TiS 2 −CNT). This novel approach of membrane-free hybrid Faradaic capacitive deionization paves the way toward energy-efficient desalination of seawater.
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