Modification effects of porphyrin dyes on the photocatalytic activity of tantalum (oxy)nitride (TaON) were investigated. The nitrogen content in tantalum (oxy)nitride was increased by increasing the heat treatment period. The optimized nitridation conditions were found to be calcination at 800 °C for 14 h under a NH 3 gas flow (25 mL min
−1). Among the porphyrin dyes examined, pentamethylene bis [4-(10,15,20-triphenylporphine-5-yl) benzoate]-dizinc (II) (Zn-TPPD) showed the most positive effect on the photocatalytic activity of TaON for H 2 production from Na 2 S aqueous solution. From the results of the photocatalytic reaction using various combinations of catalyst components, it was found that the modification dye and PtO x co-catalysts were necessary to achieving photocatalytic H 2 formation. In the PtO x /Zn-TPPD/TaON photocatalyst, the expected charge transfer mechanism was a two-step excitation of both TaON and Zn-TPPD, and the oxidation and reduction sites were TaON and PtO x co-catalyst, respectively. These results indicate that dye modification has the potential to improve the photocatalytic activity of various (oxy)nitride photocatalysts.
We studied the effects of retinal detachment surgery on the standing potential of the human eye using the electrooculographic technique. Before and two weeks after surgery, we measured the relative base value (rBV) which is the base value of the affected eye divided by the base value of the fellow eye. The rBV distributed around 1.0 before surgery and decreased below 1.0 two weeks after surgery. The change in the rBV through surgery represented by the value R is defined as preoperative rBV minus postoperative rBV divided by preoperative rBV; this was closely correlated with the area of the scleral buckling. The decrease in the rBV was thought to represent the reduction in the standing potential of the operated eye, probably due to circulatory disturbance of the choroid.
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