No abstract

No abstract

No abstract

In this study, a new green synthesis method for two-dimensional (2D) copper nanosheets is developed using methylsulfonylmethane (DMSO2). The chemical composition and light absorption of 2D copper nanosheets are also studied. A new green method is mainly to utilize DMSO2, which is environmentally friendly enough to be considered a food-grade chemical, unlike the conventional method using toxic chemicals, such as ammonia and hydrazine (N2H4). With a reducing agent, the aggregation of uncertain copper products was produced in the absence of DMSO2, while 2D copper nanosheets were formed in the presence of DMSO2. The optimum concentration of DMSO2 as a surfactant was determined to be 2 M, resulting in large surface areas with regular edges. FTIR spectrum confirmed C–H bonding from DMSO2 used to synthesize 2D copper nanosheets. The light absorption peak was revealed at 800 nm in the UV–vis spectrum. This proposed new green method not only has a simpler process than the conventional methods, such as hydrothermal method and chemical bath deposition, but also substitutes toxic chemicals with DMSO2. 2D copper nanosheets can be used for various applications, including conductive filler or ink in the flexible electronics and laser photonics fields.

The purpose of machining operations is to make specific shapes or surface characteristics for a product. Conditions for machining operations were traditionally selected based on geometry and surface finish requirements. However, nowadays, many researchers are optimizing machining parameters since high-quality products can be produced using more expensive and advanced machines and tools. There are a few methods to optimize the machining process, such as minimizing unit production time or cost or maximizing profit. This research focused on maximizing the profit of computer numerical control (CNC) milling operations by optimizing machining parameters. Cutting speeds and feed are considered as the main process variables to maximize the profit of CNC milling operations as they have the greatest effect on machining operation. In this research, the Nelder–Mead simplex method was used to maximize the profit of CNC milling processes by optimizing machining parameters. The Nelder–Mead simplex method was used to calculate best, worst, and second-worst value based on an initial guess. The possible range of machining parameters was limited by several constraints. The Nelder–Mead simplex method yielded a profit of 3.45 ($/min) when applied to a commonly used case study model.

The machining of an idealized glass fibre reinforced plastic (GFRP) was examined using photo-elasticity, dynamometry and optical microscopy. Cutting stresses at the glass roving and roving-matrix interface were evaluated using experimental and numerical methods. Experimentally observed isochromatics and measured forces in the orthogonal cutting of GFRP were shown to be affected by the reinforcement and its orientation. Machining stresses and machined surface damage were found to be highest when machining materials with roving oriented 45° towards the cutting edge.

Polycaprolactone (PCL) has been one of the most popular biomaterials in tissue engineering due to its relatively low melting temperature, excellent thermal stability, and cost-effectiveness. However, its low cell attraction, low elastic modulus, and long-term degradation time have limited its application in a wide range of scaffold studies. Dimethyl sulfone (DMSO2) is a stable and non-hazardous organosulfur compound with low viscosity and high surface tension. PCL and DMSO2 composites may overcome the limitations of PCL as a biomaterial and tailor the properties of biocomposites. In this study, PCL and DMSO2 composites were investigated as a new bio-scaffold material to increase hydrophilicity and mechanical properties and tailor degradation properties in vitro. PCL and DMSO2 were physically mixed with 10, 20, and 30 wt% of DMSO2 to evaluate thermal, hydrophilicity, mechanical, and degradation properties of the composites. The water contact angle of the composites for hydrophilicity decreased by 15.5% compared to pure PCL. The experimental results showed that the mechanical and degradation properties of PCL and DMSO2 were better than those of pure PCL, and the properties can be tuned by regulating DMSO2 concentration in the PCL matrix. The elastic modulus of the composite with 30 wt% of DMSO2 showed 532 MPa, and its degradation time was 18 times faster than that of PCL.

No abstract