This paper reports on the role of natural convection on solid–liquid interface motion and heat transfer during melting and solidification of a pure metal (gallium) on a vertical wall. The measurements of the position of the phase-change boundary as well as of temperature distributions and temperature fluctuations were used as a qualitative indication of the natural convection flow regimes and structure in the melt during phase transformation taking place in a rectangular test cell heated or cooled from one of the vertical walls. For melting, the measured melt volume and heat transfer coefficients are correlated in terms of relevant dimensionless parameters. For solidification, the measured volume of metal solidified on the wall is compared with predictions based on a one-dimensional model.
Vertically aligned TiO2 nanorods were prepared by its sol-gel which is spun coat onto aluminum anodic oxide template pregrown on an indium tin oxide glass substrate. The poly(3-hexylthiophene) (P3HT), a conjugate polymer infiltrated into the nanorod arrays, and the combined system were used as the active layer. The nanorods/P3HT solar cell with cell size of 0.06cm2 demonstrated a power conversion efficiency of 0.512% while the bilayer TiO2 film/P3HT cell was 0.12%. The current work provides fabrication method for a stable well aligned nanorods/polymer hybrid solar cell production.
Experiments are performed to study surface curvature effects on the impingement cooling flow and the heat transfer processes over a concave and a convex surface. A single air jet issuing from different size slots continuously impinges normally on the concave side or the convexside of a heated semicylindrical surface. An electrical resistance wire is used to generate smoke, which allows us to visualize the impinging flow structure. The local heat transfer Nusselt number along the surfaces is measured. For impingement on a convex surface, three-dimensional counterrotating vortices on the stagnation point are initiated, which result in the enhancement of the heat transfer process. For impingement on a concave surface, the heat transfer Nusselt number increases with increasing surface curvature, which suggests the initiation of Taylor–Go¨rtler vortices along the surface. In the experiment, the Reynolds number ranges from 6000 to 350,000, the slot-to-plate spacing from 2 to 16, and the diameter-to-slot-width ratio D/b from 8 to 45.7. Correlations of both the stagnation point and the average Nusselt number over the curved surface, which account for the surface curvature effect, are presented.
Nanocomposites, such as polymer blending with carbon nanotubes (CNTs), have been shown to have a drastic reduction in the resistivity and become conductive when the CNTs concentration has reached a certain percolation threshold. The reduction could be more than a millionth of the original polymer material. This has been realized as the formation of an infinite cluster of connected CNTs or pathways. Therefore, the conductivity of a nanocomposite should follow that of CNTs. Here we show that the resistivity of a nanocomposite is not governed by the interconnected CNTs, but the polymer between neighboring CNTs. That is, polymer-CNTs exhibit the nature of a conducting polymer, which can be explained as the tunneling of electrons one by one from the first CNT electrode to the next-nearest CNT electrode, forming a CNT/polymer pathway. A conduction model based on the tunneling of electrons passing, one by one, through the polymer gap between two neighboring CNT electrodes is formulated and derived. This model can accurately predict the significant reduction of the polymer-CNTs' resistivity with the addition of CNTs. The temperature effect can be readily incorporated to account for resistivity variation with the temperature of this nanocomposites.
This is the first time that free microjet flow dynamics is explored experimentally in the open literature. The microjet is issued from a microslot nozzle made by microelectromechanical system techniques. Three different sizes of slot nozzles that have the widths of 50, 100, and 200 m are fabricated. Careful flow visualization and instantaneous velocity measurements at different locations for these jet flows are made at different Reynolds numbers. The results indicate that the vortex formation and merging processes that occurred in the large-scale macrojet are completely absent in the microjet, and the microjet flow phenomenon is drastically different from that of the macrojet. A microjet can penetrate much deeper than a macrojet. A critical Reynolds number for the breakdown of the microjet is determined. Detailed discussion on the microjet dynamics will be presented in this paper.
Polyimide (PI)-carbon nanotube composites were fabricated by in situ polymerization using multi-wall carbon nanotubes (MWNT) as fillers. The composite film was characterized by some analytical instruments to ensure its structure and good dispersion of the MWNTs in the composites. The electrical resistivity of this composite was found to vary significantly with both the temperature and the stress in the material. The PI-MWNT composites possess a very linear piezoresistive nature which can be used as a good pressure sensor material, provided with proper temperature compensation. Fabrication of a micropolymer pressure sensor using this nanocomposite sensing material is demonstrated and sensor performance is evaluated. The sensor has a higher sensitivity than a polysilicon sensor, rapid response, and is thermally stable. The sensor is suitable for mass production, and can be widely applied or integrated in a microfluidic system or biochip where pressure information is required.
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