Strongly coupled data assimilation (SCDA) views the Earth as one unified system. This allows observations to have an instantaneous impact across boundaries such as the air‐sea interface when estimating the state of each individual component. Operational prediction centers are moving toward Earth system modeling for all forecast timescales, ranging from days to months. However, there have been few studies that examine fundamental aspects of SCDA and the transition from traditional approaches that apply data assimilation only to a single component, whether forecasts were derived from a coupled model or an uncoupled forced model. The SCDA approach is examined here in detail using numerical experiments with a simple coupled atmosphere‐ocean quasi‐geostrophic model. The impact of coupling is explored with respect to its impact on the Lyapunov spectrum and on data assimilation system stability. Different data assimilation methods are compared within the context of SCDA, including the 3‐D and 4‐D Variational methods, the ensemble Kalman filter, and the hybrid gain method. The impact of observing system coverage is also investigated. We find that SCDA is generally superior to weakly coupled or uncoupled approaches. Dynamically defined background error covariance estimates are essential for SCDA to achieve an accurate coupled state estimate as the observing system becomes sparser. As a clarification of seemingly contradictory findings from previous studies, it is shown that ocean observations can adequately constrain atmospheric state estimates provided that the analysis‐observing frequency is sufficiently high and the ensemble size determining the background error covariance is sufficiently large.

No abstract

No abstract

No abstract

Dendrobium huoshanense is a valued herbal plant used in traditional Chinese medicine. Fractionation of the water-soluble part of D. huoshanense by repeated chromatography culminated in the isolation of four new 6,8-di-C-glycosyl flavones (1-4), in addition to seven known compounds, comprising malic acid, dimethyl malate, N-phenylacetamide, isopentyl butyrate, salicylic acid, shikimic acid, and isoschaftoside. By detailed spectroscopic analysis, the structures of 1-4 were determined to have a core of apigenin bearing pentoside (arabinoside or xyloside) and rhamnosyl-hexoside (glucoside or galactoside) substituents.