This work reports the isolation of protein from defatted cashew nut shell (CNS), with the crude protein product containing 91.07% protein. Under its natural conditions, the solubility of this protein isolate is comparable (74.02%) to that of mustard green meal protein. The solubility of the protein isolate decreases with decreasing pH, with the minimum solubility observed at its isoelectric point (pH 3). The water holding capacity, oil holding capacity, foaming capacity, foam stability, emulsifying capacity and emulsion stability were found to be 2.56 cm 3 H 2 O/g protein, 4.28 cm 3 oil/g protein, 76.88%, 70.98%, 62.0% and 79.0%, respectively. The profiles of these functional properties were determined with varying pH values and NaCl concentrations, and improved properties were observed in the alkaline pH range and in the presence of NaCl. Electrophoretic analysis showed that the high molecular weight protein globulin was the major protein in the protein isolate.

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Production of diglycerides (DG) plays an important role in food, pharmaceutical, and cosmetic industries. In this study, optimal conditions for DG synthesis via noncatalyzed esterification of oleic acid with glycerol were determined. The temperatures (150°C, 175°C, and 200°C), oleic acid to glycerol molar ratios (1:1, 2:1, 3:1, and 4:1), and initial water content were varied to determine DG selectivity and % conversion over an 8‐hr period in a nitrogen‐purged system. The results exhibited a similar trend to catalyzed studies wherein an increase in temperature and molar ratio leaned towards the production of triglycerides (TG). It was also noted that tested initial water contents had an insignificant effect on reaction rates and product selectivity. Addition of molecular sieves for removal of water also resulted in negligible effects within this temperature range. DG production is optimum at 175°C and 2:1 molar ratio at 4 hr resulting in a product containing 42.6 ± 0.92 wt.% DG and a process selectivity of 1.11 ± 0.06 g DG/g (monoglycerides + TG). Purification by silica gel column chromatography of the product with the highest selectivity resulted in an enriched mixture with a yield of 58.25% and purity of 86.95 wt.% DG. Compared with catalyzed reactions, this system would require less downstream processing as removal of catalysts is not required and saponification does not occur. Although this procedure involves higher reaction temperature compared with enzyme‐catalyzed reactions, the time required to obtain high conversion is much shorter.

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This study examines sustainable agricultural development in Vietnam by focusing on rice production in the Mekong Delta. Vietnam is the third largest rice-exporting country in the world and more than 90% of rice for export is from the Mekong Delta. We attempt to identify changes in the rice industry, specifically examining farming mechanization, trends in farm operation, and farm household economy. The main structure of our study is based on our direct interviews with 420 farmer households, 81 registered large farm owners, 75 farming service providers, and local government members. We carried out those interviews in 2013 and 2014. We identified several important changes brought by technological advances, economic modernization, government policies, and environmental movements. One important finding was the increasing trend of agricultural land per farmer household, such as from 1.98 to 2.27 ha in 2010 to 2018, and the decreasing trend of labor force, which pushed up agricultural mechanization. Another point was the land law revised in 2013, which allowed farmers to borrow (no private land ownership in Vietnam) farms up to 30ha/household if registered as a “Trang Trai” farm. Farmers accepted the use of tractors and combine harvesters; however, rice seed sowing was not mechanized, so rice transplanters were rarely used for rice planting. Among the processes of rice production, sowing of rice seeds was the least mechanized. In order to achieve more sustainable agricultural practices, we recommend improving the mechanization of the rice seed sowing process for the Mekong Delta farmers with acceptable conditions. Another finding was positive movements among Mekong Delta researchers and farmers to improve their rice quality to be accepted as high-quality rice in the global rice market and to dispel the bad reputation of the past.

Our objective was to develop a process for recovering acetyl groups from industrial northeast hardwood chips. Extraction experiments showed that the white liquor charge of 6% effective alkali at 50°C and liquor-to-wood ratio of 4:1 leads to the complete extraction of acetyl groups from industrial hardwood chips. Electrodialysis was assessed as a technique for separating and concentrating sodium acetate from synthetic hardwood extract. Preliminary separation experiments using dilute sodium acetate showed that the sodium acetate can be concentrated up to approximately 24% by weight from an initial concentration of about 2% by weight. The effects of current density, feed concentration, electro-osmosis, and osmosis on the separation of sodium acetate were evaluated. Finally, selectivity experiments were performed to study the effect of various components of the white liquor on the separation of sodium acetate. Fully oxidized synthetic white liquor was used in selectivity experiments to avoid deleterious effects of Na2S. Selectivity experiments using synthetic oxidized white liquor showed a significant decrease in the separation efficiency due to the presence of sodium hydroxide, sodium carbonate, and sodium sulfate in the synthetic extract.

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