Prussian blue analogs with an open framework are ideal cathodes for Na‐ion batteries. A superior high‐rate and highly stable monoclinic nickel hexacyanoferrate (NiHCF‐3) is synthesized via a facile one‐step crystallization‐controlled co‐precipitation method. It gives a high specific capacity of 85.7 mAh g−1, nearly to its theoretical value. It also exhibits an excellent rate capability with a high capacity retention ratio of 78% at 50 C and a stable cycling performance over 1200 cycles. Through the ex situ X‐ray diffraction and pair distribution function measurements, it is found that the monoclinic structure with distorted framework is greatly related to the high Na content. The electronic structure studies by density functional theory (DFT) calculation demonstrate that NiHCF‐3 deformation promotes the framework conductivity and improves the electrochemical activity of Fe, which results in an ultrahigh‐rate performance of monoclinic phase. Furthermore, the high‐quality monoclinic (NiHCF‐3) exhibits excellent compatibility with both hard carbon and NaTi2(PO4)3 anodes in full cells, which shows great prospects for the application in the large‐scale energy storage systems.
Hard carbon (HC) is one of the most promising anode materials for sodium-ion batteries (SIBs) due to its suitable potential and high reversible capacity. At the same time, the correlation between carbon local structure and sodium-ion storage behavior is not clearly understood. In this paper, the two series of HC materials with perfect spherical morphology and tailored microstructures were designed and successfully produced using resorcinol formaldehyde (RF) resin as precursor. Via hydrothermal self-assembly and controlled pyrolysis, RF is a flexible precursor for high-purity carbon with a wide range of local-structure variation. Using these processes, one series of five representative RF-based HC nanospheres with varying degrees of graphitization were obtained from an RF precursor at different carbonization temperatures. The other series of HC materials with various microscopic carbon layer lengths and shapes was achieved by carbonizing five RF precursors with different cross-linking degrees at a single carbonization condition (1300 °C and 2 h). On the basis of the microstructures, unique electrochemical characteristics, and atomic pair distribution function (PDF) analyses, we proposed a new model of “three-phase” structural for HC materials and found triregion Na-ion storage behavior: chemi-/physisorption, intercalation between carbon layers, and pore-filling, derived from the HC phases, respectively. These results enable new understanding and insight into the sodium storage mechanism in HC materials and improve the potential for carbon-based SIB anodes.
Metal–organic frameworks (MOFs), such as Prussian blue and its analogues (PB and PBAs) with open frameworks have attracted tremendous attentions as cathode materials for sodium‐ion batteries, owing to their simple method of synthesis and high theoretical specific capacity. In this study, core–shell‐structured PBAs are prepared by an in situ self‐assembly method. Owing to the advantages of both constituents, the as‐prepared core–shell PBAs show excellent rate and cycling electrochemical properties through a dual‐level‐controlled charge–discharge depth mechanism. It delivers a specific capacity of 104.3 mAh g−1 at 0.1 C, as well as a remarkably enhanced cycle performance, giving 88.3 % of its initial capacity over 1000 cycles at 300 mA g−1. In particular, the coating strategy described herein could be extended to other MOF materials, leading to wider application in energy storage.
Due to climate variation and global warming, utilization of renewable energy becomes increasingly imperative. Rechargeable potassium-ion batteries (PIBs) have lately attracted much attention due to their earth-abundance and cost-effectiveness. Because soft carbon materials are cheap, abundant, and safe, extensive feasible research studies have indicated that they could become promising anode materials for PIBs. In spite of gaining achievements, fundamental questions regarding effects of the basic structure unit inside soft carbon on potassium storage potential have not been sufficiently addressed yet. Here, a series of soft carbon pyrolyzed from 900 to 2900 °C were systematically and quantitatively characterized by combining Raman spectroscopy, near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, X-ray pair distribution function analysis, and advanced evaluation of wide-angle X-ray scattering data. All these characterizations reveal structural details of soft carbon with increasing pyrolysis temperature. Our results show that the potassium storage behavior, especially the potential plateau is closely correlated to non-uniformity in interlayer distance and defect concentration in soft carbon, which is further confirmed by reverse Monte Carlo (RMC) modeling and density functional theory calculation. On the basis of these results, optimizing strategies are discussed to design an advanced soft carbon anode. This work provides significant insights into the structure engineering of soft carbon for high-performance rechargeable PIBs.
The cerium and/or zirconium-doped Cu/ZSM-5 catalysts (CuCe x Zr 1−x O y /ZSM-5) were prepared by ion exchange and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction by hydrogen (H 2 -TPR). Activities of the catalysts obtained on the selective catalytic reduction (SCR) of nitric oxide (NO) by ammonia were measured using temperature programmed reactions. Among all the catalysts tested, the CuCe 0.75 Zr 0.25 O y /ZSM-5 catalyst presented the highest catalytic activity for the removal of NO, corresponding to the broadest active window of 175-468 • C. The cerium and zirconium addition enhanced the activity of catalysts, and the cerium-rich catalysts exhibited more excellent SCR activities as compared to the zirconium-rich catalysts. XRD and TEM results indicated that zirconium additions improved the copper dispersion and prevented copper crystallization. According to XPS and H 2 -TPR analysis, copper species were enriched on the ZSM-5 grain surfaces, and part of the copper ions were incorporated into the zirconium and/or cerium lattice. The strong interaction between copper species and cerium/zirconium improved the redox abilities of catalysts. Furthermore, the introduction of zirconium abates N 2 O formation in the tested temperature range.that the incorporation of zirconia in cerium-based materials via high-temperature calcination can enhance the thermal stability and dispersion of the active component on the support surface [13,14]. Furthermore, the addition of zirconia to ceria introduces structural defects through substitution of Ce 4+ by Zr 4+ , which further enhances the oxygen storage capacity of ceria, the oxygen mobility in the lattice, the redox property, and thermal resistance [9,11,13]. Consequently, cerium and zirconium materials have the potential to improve the catalytic activity of Cu/ZSM-5 catalyst. Based on this background, the present work attempts to address the effects of the cerium and/or zirconium addition on Cu/ZSM-5 catalysts for SCR of NO by NH 3 . A series of CuCe x Zr 1−x O y /ZSM-5 catalysts (x = 0, 0.25, 0.50, 0.75 and 1) were synthesized using a conventional ion-exchange method, and the effects of adding cerium/zirconium metal ions into Cu/ZSM-5 catalysts on the SCR reaction were investigated using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and temperature-programmed reduction by hydrogen (H 2 -TPR). The correlation between the structural characteristics, dispersion, reduction, and activity for the SCR process are discussed. The purpose of this work is to establish the relationships between structure and catalytic performance, which will be beneficial for the design and rationalization of the practical diesel catalysts. Results and Discussion Structure and Morphology
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