Here we report a general C(sp3)–H/C(sp3)–H dehydrogenative coupling
strategy for the preparation
of various natural or unnatural amino acids from readily available
glycine derivatives and hydrocarbons through a combination of SET
and HAT process.
A redox-neutral decarboxylative radical–radical coupling reaction of heteroaryl methylamines with NHPI esters has been developed by employing a copper complex as a photocatalyst with blue LED irradiation.
Hydrofunctionalization of alkenes represents a fundamental strategy in synthetic organic chemistry. Herein, we describe a visible-light-promoted approach for the anti-Markovnikov hydrooxygenation of unactivated alkenes. Our protocol features the utilization of a cost-effective, bench-stable, and easyto-handle oxime ester as the reagent, enabled by energy-transfer catalysis. This methodology exhibits excellent functional group tolerance and mild reaction conditions, rendering it suitable for the hydroesterification of pharmaceutically relevant molecule-derived alkenes.
Correction for ‘Photocatalyzed redox-neutral decarboxylative alkylation of heteroaryl methanamines’ by Pengfei Niu et al., Green Chem., 2021, 23, 774–779, DOI: 10.1039/D0GC04094K.
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