Plasmonic enhancement induced by metallic nanostructures is an effective strategy to improve the upconversion efficiency of lanthanide-doped nanocrystals. It is demonstrated that plasmonic enhancement of the upconversion luminescence (UCL) of single NaYF :Yb /Er /Mn nanocrystal can be tuned by tailoring scattering and absorption cross sections of gold nanorods, which is synthesized wet chemically. The assembly of the single gold nanorod and single upconversion nanocrystal is achieved by the atomic force microscope probe manipulation. By selecting two kinds of gold nanorods with similar longitudinal surface plasmon resonance wavelength but different diameters (27.3 and 46.7 nm), which extinction spectra are separately dominant by the absorption and scattering, the maximum UCL enhancement by a factor of 110 is achieved with the 46.7 nm-diameter gold nanorod, while it is 19 for the nanorod with the diameter of 27.3 nm. Such strong enhancement with the larger gold nanorod is due to stronger scattering ability and greater extent of the near-field enhancement. The enhanced UCL shows a strong dependence on the excitation polarization relative to the nanorod long axis. Time-resolved measurements and finite-difference time-domain simulations unveil that both excitation and emission processes of UCL are accelerated by the nanorod plasmonic effect.

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An analogy of electromagnetically induced transparency (EIT) based on all-dielectric metamaterial is theoretically demonstrated in this paper. The U-shaped Silicon-based metamaterial unit cell comprises a dipole antenna supported by one horizontal nanoscale bar and a quadrupolar antenna supported by two vertical nanoscale bars. The near-field coupling between the two antennas and the reduction of absorption loss lead to a narrow EIT-like transmission window with a high quality-factor of 130, which exhibits a refractive index sensitivity with a figure-of-merit of 29. The group delay of 0.75 ps and the group index of 2035 are obtained in the transmission window. Due to these unique optical properties, the proposed metamaterial structure can find many applications including slow-light devices, optical sensors, enhancement of non-linear processes, and storage of quantum information.

Rare-earth ions doped upconversion nanoparticles (UCNPs) have received great attention for the promising applications ranging from bioimaging and sensing to lighting and displaying technology. Meanwhile, active control of polarization state of the upconversion luminescence (UCL) of UCNPs is also significant in the applications such as polarization microscopy and 3D display. Here, we report the polarization modification for the UCL of β-NaYF 4 :Yb 3+ ,Er 3+ nanoparticles by selectively matching the localized surface plasmon resonance (LSPR) of the rectangular plasmonic slot nanoantenna array to the spectrum of the UCL. The plasmonic resonance band centered at 650 nm of the nanoantenna array realized a strong polarization nature of the selected UCL around 660 nm with the degree of linear polarization up to ∼80%, which stems from the interaction between the 660 nm emission band of UCNPs and the plasmonic modes of the rectangular slot nanoantenna array. Meanwhile, the UCL at 550 nm remained unpolarized due to the mismatch to the plasmonic modes. The experimental results are explained well by theoretical simulations based on the local surface plasmonic resonance. Our results provide an effective way to control the anisotropic UCL of UCNPs with the applications in polarization-based imaging and 3D display technologies and so forth.

We investigate the fluorescence from submonolayer porphyrin molecules near silver-polymer core-shell nanoparticles (NPs) at a well-controlled separation distance of about 1 nm - 5 nm. When porphyrin molecules are deposited on silver NPs with the plasmonic resonance peak at about 410 nm, which matches very closely with the 405-nm excitation laser and the absorption band of porphyrin molecules, their emission intensity is found to be enhanced due to the plasmonic resonant excitation enhancement, and shows a decline as the increasing polymer shell thickness. Meanwhile, the lifetime results demonstrate that there exists the fluorescence quenching due to the charge transfer and nonradiative energy transfer losses, which is also the main reason that the maximum enhancement factor obtained in experiment is only about 2.3, although the theoretical one is above 60 according to the electric field distribution near silver NPs calculated by finite-difference time-domain method.