This paper examines the influence of CEO career horizon problems on corporate social responsibility (CSR). We assume that as CEOs are getting older, they tend to disengage in CSR due to their shorter career horizons. We further argue that high levels of industry-level discretion (ILD) and blockholder ownership amplify the negative effects of CEO age on CSR. Using a panel sample of US-based firms over 2004-2009, we do not find the main effect of CEO age on CSR, but find support for the moderating effects, such that CEO age is negatively associated with CSR when there are high levels of ILD and blockholder ownership. Therefore, results suggest that CEO career horizon problems matter for CSR when (1) CEOs have sufficient discretion over the firm's strategic decisions and (2) outside blockholders put more pressure on CEOs to engage in financial earning management.

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As typical electrode materials for supercapacitors, low specific capacitance and insufficient cycling stability of transition metal oxides (TMOs) are still the problems that need to be solved. Design of core-shell structure is considered as an effective method for preparation of high-performance electrode materials. In this work, NiO flakes@CoMoO 4 nanosheets/Ni foam (NiO flakes@CoMoO 4 NSs/NF) core-shell architecture was constructed by a two-step hydrothermal method. Interestingly, the CoMoO 4 NSs are vertically grown on the surface of NiO flakes, forming a two-dimensional (2D) branched core-shell structure. The porous core-shell architecture has relatively high surface area, effective ions channels, and abundant redox sites, resulting in excellent electrochemical performance. As a positive electrode for supercapacitors, NiO flakes@CoMoO 4 NSs/NF core-shell architecture exhibits excellent capacitive performance in terms of high specific capacitance (1097 F/g at 1 A/g) and outstanding cycling stability (97.5% after 2000 circles). The assembled asymmetric supercapacitor (ASC) of NiO flakes@CoMoO 4 NSs/NF//active carbon (AC)/NF possesses a maximum energy density of 25.8 Wh/kg at power density of 894.7 W/kg. The results demonstrate that NiO flakes@CoMoO 4 NSs/NF electrode displays potential applications in supercapacitors and the design of 2D branched core-shell architecture paves an ideal way to obtain high-performance TMOs electrodes. Electronic supplementary material The online version of this article (10.1186/s11671-019-3054-3) contains supplementary material, which is available to authorized users.

Taking into consideration short-atomic-range interactions and anharmonic effects, we calculate the thermal expansion coefficients, Gruneisen parameters, the elastic modulus of graphene varying with temperature and the phonon frequency. The anharmonic effects associated with the graphene deformation are also discussed. The results show that the value of thermal expansion coefficient is negative in the moderate temperature range, and it becomes positive when the temperature grows to be higher than a certain value. The change rate of elastic modulus with respect to temperature and pressure are calculated, and phonon frequencies are estimated. In the process of graphene thermal expansion, it is accompanied with the change of bond length and the rotation around the axis normal to the plane. Our results indicate that the effects due to the bond change are more significant than that of the rotation. We also show that if anharmonic effects are ignored, the thermal expansion coefficient and the Gruneisen parameters are zero, and the elastic modulus and the phonon frequency are constant. If anharmonic effects are considered up to the second term, these values will vary with temperature, and become closer to the experimental value. The higher the temperature is, the more significant the anharmonic effects become.

Although sheet-like materials have good electrochemical properties, they still suffer from agglomeration problems during the electrocatalytic process. Integrating two-dimensional building blocks into a hollow cage-like structure is considered as an effective way to prevent agglomeration. In this work, the hierarchical NiCo2O4 nanocages were successfully synthesized via coordinated etching and precipitation method combined with a post-annealing process. The nanocages are constructed through the interaction of two-dimensional NiCo2O4 nanosheets, forming a three-dimensional hollow hierarchical architecture. The three-dimensional supporting cavity effectively prevents the aggregation of NiCo2O4 nanosheets and the hollow porous feature provides amounts of channels for mass transport and electron transfer. As an electrocatalytic electrode for methanol, the NiCo2O4 nanocages-modified glassy carbon electrode exhibits a lower overpotential of 0.29 V than those of NiO nanocages (0.38 V) and Co3O4 nanocages (0.34 V) modified glassy carbon electrodes. The low overpotential is attributed to the prominent electrocatalytic dynamic issued from the three-dimensional hollow porous architecture and two-dimensional hierarchical feature of NiCo2O4 building blocks. Furthermore, the hollow porous structure provides sufficient interspace for accommodation of structural strain and volume change, leading to improved cycling stability. The NiCo2O4 nanocages-modified glassy carbon electrode still maintains 80% of its original value after 1000 consecutive cycles. The results demonstrate that the NiCo2O4 nanocages could have potential applications in the field of direct methanol fuel cells due to the synergy between two-dimensional hierarchical feature and three-dimensional hollow structure.