Prelithiation/presodiation techniques are regarded as indispensable procedures in electrochemical energy storage (EES) systems, which can effectively compensate irreversible capacity loss, raise working voltage, and increase Li+/Na+ concentration in the electrolyte. Various prelithiation/presodiation methods have been successfully exploited and a revolutionary impact has been achieved through the utilization of prelithiation/presodiation techniques. It is well acknowledged that different prelithiation/presodiation strategies possess their own specific mechanisms, which play vital roles in the advancement of EES systems. However, there has rarely been systematical reviews about the concept and progress of prelithiation/presodiation techniques. Hence, in this review various prelithiation/presodiation approaches are comprehensively analyzed and summarized, and in‐depth prelithiation/presodiation behaviors and other innovative applications (including optimization of separators, amelioration of binders, regeneration of spent batteries) are discussed in detail. Finally, suggested future directions of prelithiation/presodiation techniques are proposed and it is expected that these prelithiation/presodiation techniques could provide guidance for construction of advanced EES systems and propel the commercialization process with a focus on safety considerations.
Ameliorating the interfacial issues of the zinc anode, particularly dendrite growth and electrode corrosion, is imperative for rechargeable zinc metal batteries. Herein, an electrochemical-inert liquid gallium–indium alloy coating is designed toward the zinc anode, inspired by the gallium–indium–zinc phase diagram. This unique liquid coating prefers an inward-deposition of Zn underneath the liquid coating assisted by ultrafast mass/charge transport when charging. Moreover, the corrosion of the modified zinc anode is improved as well, depiciting a hydrogen-evolution reaction overpotential higher than that of the reference zinc anode. Consequently, it enables a polarization of 24 mV, the lowest to the best of our knowledge, at 0.25 mA cm–2 with a prolonged lifespan (2100 h), which further enables the corresponding MnO2 full cells with improved capacity retention and stage of charge above 96% after 48 h. This effective approach provides a universal idea for the future development of rechargeable metal batteries beyond zinc-storage systems.
Transition-metal selenides have captured sustainable research attention in energy storage and conversion field as promising anodes for sodium-ion batteries. However, for the majority of transition metal selenides, the potential windows have to compress to 0.5–3.0 V for the maintenance of cycling and rate capability, which largely sacrifices the capacity under low voltage and impair energy density for sodium full batteries. Herein, through introducing diverse metal ions, transition-metal selenides consisted of different composition doping (CoM–Se2@NC, M = Ni, Cu, Zn) are prepared with more stable structures and higher conductivity, which exhibit superior cycling and rate properties than those of CoSe2@NC even at a wider voltage range for sodium ion batteries. In particular, Zn2+ doping demonstrates the most prominent sodium storage performance among series materials, delivering a high capacity of 474 mAh g–1 after 80 cycles at 500 mA g–1 and rate capacities of 511.4, 382.7, 372.1, 339.2, 306.8, and 291.4 mAh g–1 at current densities of 0.1, 0.5, 1.0, 1.4, 1.8, and 2.0 A g–1, respectively. The composition adjusting strategy based on metal ions doping can optimize electrochemical performances of metal selenides, offer an avenue to expand stable voltage windows, and provide a feasible approach for the construction of high specific energy sodium-ion batteries.
The lack of methods to modulate intrinsic textures of carbon cathode has seriously hindered the revelation of in-depth relationship between inherent natures and capacitive behaviors, limiting the advancement of lithium ion capacitors (LICs). Here, an orientated-designed pore size distribution (range from 0.5 to 200 nm) and graphitization engineering strategy of carbon materials through regulating molar ratios of Zn/Co ions has been proposed, which provides an effective platform to deeply evaluate the capacitive behaviors of carbon cathode. Significantly, after the systematical analysis cooperating with experimental result and density functional theory calculation, it is uncovered that the size of solvated PF6− ion is about 1.5 nm. Moreover, the capacitive behaviors of carbon cathode could be enhanced attributed to the controlled pore size of 1.5–3 nm. Triggered with synergistic effect of graphitization and appropriate pore size distribution, optimized carbon cathode (Zn90Co10-APC) displays excellent capacitive performances with a reversible specific capacity of ~ 50 mAh g−1 at a current density of 5 A g−1. Furthermore, the assembly pre-lithiated graphite (PLG)//Zn90Co10-APC LIC could deliver a large energy density of 108 Wh kg−1 and a high power density of 150,000 W kg−1 as well as excellent long-term ability with 10,000 cycles. This elaborate work might shed light on the intensive understanding of the improved capacitive behavior in LiPF6 electrolyte and provide a feasible principle for elaborate fabrication of carbon cathodes for LIC systems.
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