We investigate the chemical stability of CO 2-dominated atmospheres of desiccated M dwarf terrestrial exoplanets using a one-dimensional photochemical model. Around Sun-like stars, CO 2 photolysis by Far-UV (FUV) radiation is balanced by recombination reactions that depend on water abundance. Planets orbiting M dwarf stars experience more FUV radiation, and could be depleted in water due to M dwarfs' prolonged, high-luminosity pre-main sequences. We show that, for water-depleted M dwarf terrestrial planets, a catalytic cycle relying on H 2 O 2 photolysis can maintain a CO 2 atmosphere. However, this cycle breaks down for atmospheric hydrogen mixing ratios <1 ppm, resulting in ∼40% of the atmospheric CO 2 being converted to CO and O 2 on a timescale of 1 Myr. The increased O 2 abundance leads to high O 3 concentrations, the photolysis of which forms another CO 2regenerating catalytic cycle. For atmospheres with <0.1 ppm hydrogen, CO 2 is produced directly from the recombination of CO and O. These catalytic cycles place an upper limit of ∼50% on the amount of CO 2 that can be destroyed via photolysis, which is enough to generate Earth-like abundances of (abiotic) O 2 and O 3. The conditions that lead to such high oxygen levels could be widespread on planets in the habitable zones of M dwarfs. Discrimination between biological and abiotic O 2 and O 3 in this case can perhaps be accomplished by noting the lack of water features in the reflectance and emission spectra of these planets, which necessitates observations at wavelengths longer than 0.95 μm.
A High-performance Atmospheric Radiation Package (HARP) is developed for studying multiplescattering planetary atmospheres. HARP is an open-source program written in C++ that utilizes high-level data structure and parallel-computing algorithms. It is generic in three aspects. First, the construction of the model atmospheric profile is generic. The program can either take in an atmospheric profile or construct an adiabatic thermal and compositional profile, taking into account the clouds and latent heat release due to condensation. Second, the calculation of opacity is generic, based on line-by-line molecular transitions and tabulated continuum data, along with a table of correlated-k opacity provided as an option to speed up the calculation of energy fluxes. Third, the selection of the solver for the radiative transfer equation is generic.The solver is not hardwired in the program. Instead, based on the purpose, a variety of radiative transfer solvers can be chosen to couple with the atmosphere model and the opacity model.We use the program to investigate the radiative heating and cooling rates of all four giant planets in the Solar System. Our Jupiter's result is consistent with previous publications. Saturn has nearly perfect balance between the heating rate and cooling rate. Uranus has the least radiative fluxes because of the lack of CH4 and its photochemical products. Both Uranus and Neptune suffer from a severe energy deficit in their stratospheres. Possible ways to resolve this issue are discussed. Finally, we recalculate the radiative time constants of all four giant planet atmospheres and find that the traditional values from (Conrath BJ, Gierasch PJ, Leroy SS. Temperature and Circulation in the Stratosphere of the Outer Planets. Icar. 1990;83:255-81) are significantly overestimated.
A new non-hydrostatic and cloud-resolving atmospheric model is developed for studying moist convection and cloud formation in planetary atmospheres. It is built on top of the Athena++ framework, utilizing its static/adaptive mesh-refinement, parallelization, curvilinear geometry, and dynamic task scheduling. We extend the original hydrodynamic solver to vapors, clouds, and precipitation. Microphysics is formulated generically so that it can be applied to both Earth and Jovian planets. We implemented the Low Mach number Approximate Riemann Solver (LMARS) for simulating low speed atmospheric flows in addition to the usual Roe and HLLC Riemann solvers. Coupled with a fifthorder Weighted Essentially Nonoscillatory (WENO) subgrid-reconstruction method, the sharpness of critical fields such as clouds is well-preserved, and no extra hyperviscosity or spatial filter is needed to stabilize the model. Unlike many atmospheric models, total energy is used as the prognostic variable of the thermodynamic equation. One significant advantage of using total energy as a prognostic variable is that the entropy production due to irreversible mixing process can be properly captured. The model is designed to provide a unified framework for exploring planetary atmospheres across various conditions, both terrestrial and Jovian. First, a series of standard numerical tests for Earth's atmosphere is carried out to demonstrate the performance and robustness of the new model. Second, simulation of an idealized Jovian atmosphere in radiative-convective equilibrium shows that 1) the temperature gradient is superadiabatic near the water condensation level because of the changing of the mean molecular weight, and 2) the mean profile of ammonia gas shows a depletion in the subcloud layer down to nearly 10 bars. Relevance to the recent Juno observations is discussed.
Motivated by the recent detection of propene (C 3 H 6) in the atmosphere of Titan, we use a one-dimensional Titan photochemical model with an updated eddy diffusion profile to systematically study the vertical profiles of the stable species in the C 3-hydrocarbon family. We find that the stratospheric volume mixing ratio of propene (C 3 H 6) peaks at 150 km with a value of 5 × 10 −9 , which is in good agreement with recent observations by the Composite Infrared Spectrometer on the Cassini spacecraft. Another important species that is currently missing from the hydrocarbon family in Titan's stratosphere is allene (CH 2 CCH 2), an isomer of methylacetylene (CH 3 C 2 H). We predict that its mixing ratio in the stratosphere is about 10 −9 , which is on the margin of the detection limit. CH 2 CCH 2 and CH 3 C 2 H equilibrate at a constant ratio in the stratosphere by hydrogen-exchanging reactions. Thus, by precisely measuring the ratio of CH 2 CCH 2 to CH 3 C 2 H, the abundance of atomic hydrogen in the atmosphere can be inferred. No direct yield for the production of cyclopropane (c-C 3 H 6) is available. From the discharge experiments of Navarro-González & Ramírez, the abundance of cyclopropane is estimated to be 100 times less than that of C 3 H 6 .
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