1′,2′-j]picene (DDP, 1), a thermally and chemically stable helical arene, can be prepared from 1,4-bis[2-(arylethynyl)phenyl]benzene in four synthetic steps. Its helical backbone, which incorporates an oquinodimethane moiety, was verified by X-ray crystallography, and this structural feature results in a very high barrier to racemization (exceeding 50 kcal/mol). DDP possesses versatile and promising properties, including a small HOMO−LUMO energy gap (1.31 eV for the dimesitylsubstituted derivative 1ab), an electron spin resonance (ESR)active character, a small triplet−singlet energy gap (4.75 kcal/mol), broad photoabsorption covering the ultraviolet, visible, and near-infrared (NIR) regions, two-photon absorption in the NIR range, and respectable ambipolar charge-transport behavior in a solution-processed organic field-effect transistor.

Electroosmotic flow in microchannels is restricted to low Reynolds number regimes. Since the inertia forces are extremely weak in such regimes, turbulent conditions do not readily develop, and hence species mixing occurs primarily as a result of diffusion. Consequently, achieving a thorough species mixing generally relies upon the use of extended mixing channels. This paper aims to improve the mixing performance of conventional side channel type micromixers by specifying the optimal driving voltages to be applied to each channel. In the proposed approach, the driving voltages are identified by constructing a simple theoretical scheme based on a 'flow-rate-ratio' model and Kirchhoff's law. The numerical and experimental results confirm that the optimal voltage control approach provides a better mixing performance than the use of a single driving voltage gradient.

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Shear-wave velocities (V S ) have been widely used for the site characterization of earthquake ground motion. We report here our investigation of the S-wave velocity structures of Chia-Yi City, Taiwan using the array records of microtremors at seven sites. The dispersion curves at these sites were first calculated using the F-K method proposed by Capon (1969); the S-wave velocity structures in Chia-Yi City were then estimated by employing the surface wave inversion technique (Herrmann, 1991). At frequencies lower than about 1 Hz, the propagation directions are concentrated in the northwest and southwest quadrants. The generation of these may be attributed to the ocean waves of the Taiwan Strait. The harder site (CBA) has higher phase velocities, while the softer sites (CWB, SHP and YRU) have lower phase velocities, especially at frequencies between 1 and 5 Hz. The shallow velocity structures (0-1,500 m) can be roughly divided into four to five layers. The depth of the alluvium gradually increases from east to west and from north to south.

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We have conducted microtremor array measurements to estimate shallow S-wave velocity ([Formula: see text]) structures at two sites (the 921 Earthquake Museum of Taiwan and the Taiwan Provincial Consultative Council) located near surface ruptures of the Chelungpu Fault. Ten stations, consisting of three different-aperture triangles and a central station, are adopted for each array deployment. Using the array data, we calculate dispersion curves of Rayleigh waves using the frequency-wavenumber spectrum method and then estimate [Formula: see text] structures by the surface-wave inversion technique. The obtained 2D [Formula: see text] profiles could clearly show compressive and flexural deformation structures with the surface ruptures located at relatively weak (low [Formula: see text]) zones. This indicates compressive buckling as the most likely mechanism for surface rupturing along these low [Formula: see text] zones. Importantly, this study successfully depicts strata disturbances in a fault fracture zone using microtremor array measurements and forward numerical modeling of trishear fault-propagation folds.

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