Many studies reveal strong interrater agreement for Hare's Psychopathy Checklist-Revised (PCL-R) when used by trained raters in research contexts. However, no systematic research has examined agreement between PCL-R scores from independent clinicians who are retained by opposing sides in adversarial legal proceedings. We reviewed all 43 sexual-offender civil-commitment trials in one state and identified 23 cases in which opposing evaluators reported PCL-R total scores for the same individual. Differences between scores from opposing evaluators were usually in a direction that supported the party who retained their services. These score differences were greater in size than would be expected based on the instrument's standard error of measurement or the rater agreement values reported in previous PCL-R research. The intraclass correlation for absolute agreement for the PCL-R Total score from a single rater (ICC 1,A = .39) was well below levels of agreement observed for the PCL-R in research contexts, and below published test-retest values for the PCL-R. Results raise concerns about the potential for a forensic evaluator's "partisan allegiance" to influence PCL-R scores in adversarial proceedings.
Enhanced efficiency fertilisers (EEFs) may have an important role in improving nitrogen (N) use efficiency in agricultural systems. The performance of EEFs when applied by broadcasting and incorporation is well documented; however, little information is available for sub-surface banded N-fertiliser. This study aimed to determine the effectiveness of EEFs within the fertosphere in several soils. This was determined by: (i) establishing the key chemical effects and N-transformation activity within a urea band, and (ii) contrasting these findings with nitrification inhibitor (NI)-coated urea and a controlled-release polymer-coated urea (PCU). A 112-day incubation experiment was conducted with the EEFs band-applied in three contrasting soils with a history of sugarcane production. In standard urea and NI-urea treated soils, the pH within the fertosphere significantly increased to a maximum of ~pH 9.2–9.3. Alkaline conditions and high ammonium concentrations promoted elevated aqueous ammonia concentrations, resulting in complete nitrification inhibition. The PCU granules released ~40% of total urea content within 14 days, followed by subsequent release at significantly lower rates. The initial rapid urea release was attributed to damaged polymer coats, while close proximity of neighbouring granules within the band may have contributed to the subsequent slower release phase through reduced concentration gradients and restricted diffusion from granules. Variation between soils suggests that soil properties such as clay content and pH buffer capacity may influence urea hydrolysis, but not nitrification. These results suggest that both NI and controlled-release technology may not have the expected impacts on N transformations and availability when applied in a concentrated band.
Australian native species grow competitively in nutrient limited environments, particularly in nitrogen (N) limited soils; however, the mechanism that enables this is poorly understood. Biological nitrification inhibition (BNI), which is the release of root exudates into the plant rhizosphere to inhibit the nitrification process, is a hypothesized adaptive mechanism for maximizing N uptake. To date, few studies have investigated the temporal pattern and components of root exudates by Australian native plant species for BNI. This study examined root exudates from two Australian native species, Hibiscus splendens and Solanum echinatum, and contrasted with exudates of Sorghum bicolor, a plant widely demonstrated to exhibit BNI capacity. Root exudates were collected from plants at two, four, and six weeks after transplanting to solution culture. Root exudates contained three types of organic acids (OAs), oxalic, citric and succinic acids, regardless of the species. However, the two Australian natives species released larger amount of OAs in earlier development stages than S. bicolor. The total quantity of these OAs released per unit root dry mass was also seven-ten times greater for Australian native plant species compared to S. bicolor. The root exudates significantly inhibited nitrification activity over six weeks’ growth in a potential nitrification assay, with S. echinatum (ca. 81% inhibition) > S. bicolor (ca. 80% inhibition) > H. splendens (ca. 78% inhibition). The narrow range of BNI capacity in the study plants limited the determination of a relationship between OAs and BNI; however, a lack of correlation between individual OAs and inhibition of nitrification suggests OAs may not directly contribute to BNI. These results indicate that Australian native species generate a strongly N conserving environment within the rhizosphere up to six weeks after germination, establishing a competitive advantage in severely N limited environments.
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