In 2010, the Deepwater Horizon accident released 4.6–6.0 × 10(11) grams or 4.1 to 4.6 million barrels of fossil petroleum derived carbon (petrocarbon) as oil into the Gulf of Mexico. Natural abundance radiocarbon measurements on surface sediment organic matter in a 2.4 × 10(10) m(2) deep-water region surrounding the spill site indicate the deposition of a fossil-carbon containing layer that included 1.6 to 2.6 × 10(10) grams of oil-derived carbon. This quantity represents between 0.5 to 9.1% of the released petrocarbon, with a best estimate of 3.0–4.9%. These values may be lower limit estimates of the fraction of the oil that was deposited on the seafloor because they focus on a limited mostly deep-water area of the Gulf, include a conservative estimate of thickness of the depositional layer, and use an average background or prespill radiocarbon value for sedimentary organic carbon that produces a conservative value. A similar approach using hopane tracer estimated that 4–31% of 2 million barrels of oil that stayed in the deep sea settled on the bottom. Converting that to a percentage of the total oil that entered into the environment (to which we normalized our estimate) converts this range to 1.8 to 14.4%. Although extrapolated over a larger area, our independent estimate produced similar values.
Escanaba Trough is the southernmost segment of the Gorda Ridge and is filled by sandy turbidites locally exceeding 500 m in thickness. New results from Ocean Drilling Program (ODP) Sites 1037 and 1038 that include accelerator mass spectrometry (AMS) 14C dates and revised petrographic evaluation of the sediment provenance, combined with high-resolution seismic-reflection profiles, provide a lithostratigraphic framework for the turbidite deposits. Three fining-upward units of sandy turbidites from the upper 365 m at ODP Site 1037 can be correlated with sediment recovered at ODP Site 1038 and Deep Sea Drilling Program (DSDP) Site 35. Six AMS 14C ages in the upper 317 m of the sequence at Site 1037 indicate that average deposition rates exceeded 10 m/k.yr. between 32 and 11 ka, with nearly instantaneous deposition of one approximately 60-m interval of sand. Petrography of the sand beds is consistent with a Columbia River source for the entire sedimentary sequence in Escanaba Trough. High-resolution acoustic stratigraphy shows that the turbidites in the upper 60 m at Site 1037 provide a characteristic sequence of key reflectors that occurs across the floor of the entire Escanaba Trough. Recent mapping of turbidite systems in the northeast Pacific Ocean suggests that the turbidity currents reached the Escanaba Trough along an 1100-km-long pathway from the Columbia River to the west flank of the Gorda Ridge. The age of the upper fining-upward unit of sandy turbidites appears to correspond to the latest Wisconsinan outburst of glacial Lake Missoula. Many of the outbursts, or jökulhlaups, from the glacial lakes probably continued flowing as hyperpycnally generated turbidity currents on entering the sea at the mouth of the Columbia River.
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Late Quaternary paleotemperatures and paleosalinities of surface waters of the Gulf of Mexico were estimated using a multivariate statistical analysis of census data of planktonic foraminifera. Two climatic extremes were selected for detailed basinwide study, the climatic optimum 125,000 yr ago and the glacial maximum 18,000 yr ago. In addition, patterns of climatic change were examined in seven piston cores from 127,000 yr ago to the present day. During the climatic optimum 125,000 yr ago temperature distributions in surface waters were similar to those of the present. The 22°C winter isotherm trended northeastward across the central basin and paleotemperatures decreased northward. Summer distributions were nearly homogeneous and ranged between 28° and 29°C. Winter salinities were 1‰ fresher than present values in the northmost Gulf and 0.4‰ fresher in the central basin. Summer salinities were similar during both times. In contrast, during the last glacial maximum temperatures were 1° to 2°C cooler in winter and 1°C cooler in summer, and isotherms formed a circular pattern in the Gulf during both seasons. Salinity was 0.3‰ fresher in winter than at present but 0.6‰ saltier in summer. Conditions deteriorated from the climatic optimum to the glacial maximum. In the Mexico Basin, winter temperatures were 2°C cooler from 75,000 to 45,000 yr ago (Y6 to Y3 Subzones), summer temperatures reached a minimum (3°C cooler) 32,000 yr ago (Y2–Y3 boundary), and seasonality reached minimal values (5°C) from 45,000 to 15,000 yr ago. All three parameters became similar in value to those in the Straits of Florida from 45,000 to 15,000 yr ago, suggesting that the exchange of surface waters was enhanced at this time between the two regions. Summer salinities remained similar to present conditions in the Mexico Basin, whereas, winter salinities increased 2‰ by 32,000 yr ago and then fell 0.5‰ until the glacial maximum ended. The Westerlies may have migrated southward over the Mexico Basin in winter from 32,000 to 15,000 yr ago.
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