Dimethyl Ether Enhanced Waterflood (DEW) is a novel and promising solvent-based EOR technology developed by Shell. Dimethyl Ether (DME) is a widely-used industrial chemical which is applied as a water soluble solvent for EOR applications to enhance a conventional waterflood. Once the DME-brine solution is injected into the reservoir and comes in contact with the oil, the DME molecules partition into the oil phase which leads to oil swelling and mobilization of residual oil. Moreover the partitioning of the DME into the oil phase decreases the oil viscosity and improves its mobility. The combination of these effects results in both a significantly higher ultimate oil recovery compared to the conventional waterflood as well as accelerated oil production at lower energy footprint compared to thermal technologies. As the solvent is water soluble, it can be very effectively back-recovered from the reservoir by re-dissolving the trapped DME in the DME-free chase water slug. The solvent is recovered from the produced oil and water streams at surface and re-used. The main objectives of this paper are to present the first experimental results, explain the physical mechanisms of this novel concept and demonstrate the extra oil recovery. Additionally, modeling workflows used to interpret the experiments and predict the benefits of field EOR application are illustrated.To gain an insight into physical mechanisms behind the DEW, develop modeling workflows and de-risk the technology, an extensive experimental program was set up to investigate both the fluid-fluid and rock-fluid interactions. Phase behavior of DME/brine and DME/crude mixtures has been carried out, with a focus on the partitioning of the solvent between brine and crude. Mixing rules for properties affecting the phase mobilities have been determined. In parallel, a number of coreflood experiments were conducted on both carbonate and clastic cores of varying permeability to investigate the dynamic DME/crude behavior and DME/rock interaction. PVT experiments were used to build phase equilibrium models. Based on these PVT models, the coreflood experimental data was matched and interpreted using numerical simulation.Coreflood experiments confirmed the phase behavior-driven character of the DEW technology. A good match between the experimental and simulated oil recovery was obtained in most cases. This shows that PVT models, generated using measured basic data, are in a good agreement with the dynamic coreflood experiments.
In this paper we present a Shell developed, chemical EOR technique in which dimethyl ether (DME), a widely-used industrial compound, is utilised as a miscible solvent in conjunction with conventional waterflooding. The technology, laboratory results, PVT workflows and numerical aspects of DME enhanced waterflooding have been reported recently. This paper describes various aspects of upscaling from pattern scale production to field scale while conforming to various development constraints.In a DME enhanced waterflood, advantage is taken of DME's solubility in water and miscibility with hydrocarbons: water is used as a carrier for DME during injection and upon contact with reservoir fluids, DME preferentially partitions into the hydrocarbon phase thereby swelling and mobilising the oil phase. This is followed by a DME-free water chase to recover the remaining mobile oil and DME. Residual oil saturation after sweep is reduced, significantly below that typically achieved by waterflood alone. Furthermore, the DME can be extracted from the produced wellstream fluids by partly non-standard operations such as stripping, distillation and/or absorption processes, and re-used for injection.The DME Enhanced Waterflooding (DEW) technique takes advantage of the unique solubility properties of dimethyl ether to improve oil mobility and reduce residual oil saturations. Significant research into the pressure-volume-temperature (PVT) behaviour of DME and DME/crude oil mixtures has been carried out in recent years of which a summary is reported by Groot et al. (2016); in particular the partitioning behaviour of the solvent and mixing rules for the various mass transfer properties affecting mobility. The PVT-driven behaviour and the overall displacement efficiency of the DEW technique have been observed in core flood experiments using both carbonate and clastic core plugs.Considering the application of the DEW technique to a tertiary field development, the practical realities of solvent flooding become more apparent. In field developments that involve the injection of DME and solvents in general, solvent recycling and reinjection is mostly required. This is a result of the inherently high value of the solvents and is needed to increase the utilization of the solvents manufactured locally or imported. This paper describes the requirements from both subsurface as well as surface point of view to make a successful field solvent EOR development possible.
In this paper we present a novel Chemical EOR technique in which dimethyl ether (DME), a widely-used industrial compound is utilised as a miscible solvent in conjunction with conventional waterflooding. The end effect of the solvent's application is an increase in oil recovery significantly greater than that typically achieved by waterflood alone. The method of application is straightforward, taking advantage of DME's solubility in both water and hydrocarbons: water is used as a carrier for DME during injection and upon contact with reservoir fluids, DME preferentially partitions into the hydrocarbon phase thereby swelling and mobilising the oil phase. This is followed by a DME-free water chase to recover the remaining mobile oil and DME. Residual oil saturation after sweep is reduced, significantly below that typically achieved by waterflood alone. Furthermore, the DME can be extracted from the produced wellstream fluids by distillation and/or absorption processes, and re-used for injection. The DME Enhanced Waterflooding (DEW) technique takes advantage of the unique solubility properties of dimethyl ether to improve oil mobility and reduce residual oil saturations. Significant research into the pressure-volume-temperature (PVT) behaviour of DME and DME/crude oil mixtures has been carried out in recent years; in particular the partitioning behaviour of the solvent and mixing rules for the various mass transfer properties affecting mobility. The PVT-driven behaviour and the overall displacement efficiency of the DEW technique have been observed in core flood experiments using both carbonate and clastic core plugs. The DEW technique can be deployed in reservoirs with different geologies, fluid properties and conditions (pressure, temperature and salinity), making its application envelope much larger than that of any of the currently available EOR technologies.
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