This study illustrates test results and comparative literature data on the influence of isothermal aging and thermal cycling associated with Sn-1.0Ag-0.5Cu (SAC105) and Sn-3.0Ag-0.5Cu (SAC305) ball grid array (BGA) solder joints finished with ENIG and ENEPIG on the board side and ENIG on the package side compared with ImAg plating on both sides. The resulting degradation data suggests that the main concern for 0.4 mm pitch 10 mm package size BGA is package side surface finish, not board side. That is, ENIG performs better than immersion Ag for applications involving long-term isothermal aging. SAC305, with a higher relative fraction of Ag3Sn IMC within the solder, performs better than SAC105. SEM and polarized light microscope analysis show cracks propagated from the corners to the center or even to solder bulk, which eventually causes fatigue failure. Three factors are discussed: IMC, grain structure, and Ag3Sn particle. The continuous growth of Cu-Sn intermetallic compounds (IMC) and grains increase the risk of failure, while Ag3Sn particles seem helpful in blocking the crack propagation.
This study illustrates test results and comparative literature data on the influence of isothermal aging and thermal cycling associated with Sn-1.0Ag-0.5Cu (SAC105) and Sn-3.0Ag-0.5Cu (SAC305) ball grid array (BGA) solder joints finished with ImAg, ENIG and ENEPIG on board side. The resulting degradation data suggests that ENIG is the best surface finish for applications involving long-term isothermal aging. ENEPIG ranks second, followed by ImAg. SAC305, with a higher relative fraction of Ag3Sn IMC within the solder, performs better than SAC105. SEM and polarized light microscope analysis show most cracks happened at package side, propagated from corner to center or even to solder bulk, which eventually cause fatigue failures. Three factors are discussed: IMC, Grain Structure and Ag3Sn particle. The continuous growth of Cu-Sn intermetallic compounds (IMC) and grains increase the risk of failure, while Ag3Sn particle seems helpful to block the crack propagation.
Pb-free solder joints undergo microstructural and mechanical evolution due to alloy coarsening and growing intermetallic compounds which degrade the joint electrical performance. Electronics assemblies containing solder joints are frequently exposed to elevated temperatures for prolonged periods of time. The purpose of the study is to discover the effect of isothermal aging on the reliability of Sn-Ag-Cu (SAC) assemblies. After studied different surface finishes, we employed Immersion Ag (ImAg), Immersion Sn (ImSn), Electroless Ni/Immersion Au (ENIG) and Electroless Ni/Electroless Pd/Immersion Au (ENEPIG) which have potential for higher reliability and better performance and received increased attention for both packaging and subtracted applications. A full experiment matrix with varying aging temperatures and solder alloys was considered. Package sizes ranged from 19mm, 0.8mm pitch ball grid arrays (BGAs) to 5mm, 0.4mm pitch μBGAs and in additional, 0.65mm MLF and 2512 resistors be particularly tested. Storage condition are temperatures leveling up from 25°C, 55°C, 85°C, 100°C and 125 °C with aging over time periods of 0, 21 days, 6 months, 12 months and 24 months. Afterwards, the specimens all subjected to accelerated thermally cycled from −40°C to 125°C with 15 min dwell times at the high and low peak temperature. The paper presents the experimental data to justify the investigation of the degradation on the characteristic lifetime of SAC alloy on ImAg and ImSn surface finish in elevated temperature environments.
This study illustrates test results and comparative literature data on the influence of isothermal aging and thermal cycling associated with Sn-1.0Ag-0.5Cu (SAC105) and Sn-3.0Ag-0.5Cu (SAC305) ball grid array (BGA) solder joints on three board finishes (ImAg, ENIG, ENEPIG). The resulting degradation shows that the characteristic lifetimes for both SAC105 and SAC305 decrease in the order ENIG > ENEPIG > ImAg. SAC305, with a higher relative fraction of Ag3Sn IMC within the solder, performs better than SAC105. SEM and EDX analysis shows continuous growth of Cu-Sn intermetallic compounds (IMC) on SAC/ImAg systems and Cu-Ni-Sn IMC on SAC/ENIG/ENEPIG systems at board side solder joints, which eventually cause fatigue failures.
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