A uniaxial‐stretched poly(ε‐caprolactone)/poly(propylene carbonate; PCL / PPC ) composite film was prepared using a twin‐screw extruder, and its utility as an equilibrium‐modified atmosphere packaging ( EMAP ) film extending the shelf life of garland chrysanthemums stored at 2~4°C was explored. The oxygen, carbon dioxide, and water vapor penetration properties, mechanical properties, and gas permselectivity of PCL / PPC film used to package garland chrysanthemums were determined and compared to those of controlled low‐density polyethylene ( LDPE ) and PCL films. Physicochemical properties such as package headspace gas composition, weight loss, leaf color, total chlorophyll content, ascorbic acid content, lipid peroxidation extent, and the sensory traits of garland chrysanthemums were investigated over a storage period of 14 days to compare the preservative effects of the various packages. PPC blending decreased the PCL gas and water vapor permeability and slightly increased the CO 2 permselectivity. These effects on gas and water vapor permeability, combined with the effects on gas permselectivity, enhanced preservation of packed garland chrysanthemums. Furthermore, an O 2 inner atmosphere level of 2%~5%, and a CO 2 concentration not greater than 8%, was established by the PCL / PPC film in the absence of condensation. The results thus suggest that biodegradable film can be used as an EMAP film to better maintain the quality of freshly harvested garland chrysanthemums and to afford a longer shelf life during cold storage compared to LDPE film. Sensory evaluation indicated that the garland chrysanthemums were market‐acceptable after 14 days of storage; LDPE ‐packed chrysanthemums were acceptable only up to 8 days of storage. The film thus improved storage life compared to that afforded by LDPE .
To improve the added value of lignin, the modified alkali lignin of wheat straw was used to prepare waterborne UV-curable polyurethane. The purpose of this paper is to discuss the properties of the cured films made from the above lignin-based polyurethane. The mechanical and optical properties of the cured films were investigated. Results showed that the tensile storage modulus, tensile loss modulus, and tensile loss factor of the cured film were influenced by the addition of the lignin, which indicated that proper dosage of the lignin could change the micro-phase separation structure and improve the mechanical properties of the product. The addition of the lignin also influenced the gloss and light transmittance of the cured film. On the whole, the lignin-based polyurethane exhibits good mechanical and optical performance if proper proportion of the lignin was added to the product. The study was beneficial for utilizing the lignin in high value products.
The bonding mechanism between water-based UV curable ink and active groups on paper’s fiber during curing process was studied in this paper. Low viscosity water-based UV-cured resin was synthesized by epoxy resins, epoxy diluent, acrylic acid and maleic anhydride in the presence of catalyst. The viscosity of the synthesis system and synthetic products were significantly reduced when epoxy diluent was added to replace parts of the epoxy resin. Epoxy diluent was very useful in reducing the viscosity of the product, but over-dose would have negative effects on the quality of the cured film. The water-based epoxy acrylate prepolymer was used as the substitution for the ink to investigate the binding mechanism between the active groups of prepolymer and fiber under UV irradiation. The prepolymer and photoinitiator were mixed and the mixture was diluted to an appropriate viscosity by a small amount of water, then printed on the paper by the method of analog printing and curred by UV curing machine. The printed paper was used to extract lignin by enzymatic/mild acidolysis. FT-IR was used to characterize the changes of the active groups in lignin. The results showed that the changes of active groups in lignin were founded in the existence of ultraviolet and photoinitiator, which consistent with the change of double bonds in prepolymer. The free radicals produced by photoinitiator in curing process not only promoted the double bonds to polymerize, but also accelerated the active groups of lignin binding. Experiments show that chemical bonds exist between them.
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