Many advanced physical properties can be realized by using well-designed acoustic metamaterial (AM) structures, which have significant application value in engineering. In particular, thin-walled membrane, plate, and shell-type structures with deep subwavelength thicknesses that can meet light weight requirements have attracted the attention of many researchers and engineers from various specialized fields. This Tutorial systematically introduced the structural design methods, acoustic/elastic wave attenuation and regulation principles, and engineering applications of thin-walled AMs for low-frequency sound insulation, sound absorption, and vibration reduction. In particular, the design methods and sound insulation/absorption properties of thin-walled AMs for realizing narrow-band and broadband sound attenuation were explored. Furthermore, the local resonance bandgap characteristics, quantitative extraction method for the bending wave bandgap, vibration suppression properties, and the design method for local resonance vibration dampers for elastic wave regulation by thin-walled elastic metamaterials were summarized successively. Moreover, other thin-walled AM applications, such as the wavefront steering performance of thin-walled acoustic/elastic metasurfaces, and the active thin-walled AMs, were introduced as well.

A hybrid structure gas sensor of reduced graphene oxide (RGO) decorated graphene (RGO-Gr) is designed for ultra-low concentration ammonia detection. The resistance value of the RGO-Gr hybrid is the indicator of the ammonia concentration and controlled by effective charge transport from RGO to graphene after ammonia molecule adsorption. In this hybrid material, RGO is the adsorbing layer to catch ammonia molecules and graphene is the conductive layer to effectively enhance charge/electron transport. Compared to a RGO gas sensor, the signal-to-noise ratio (SNR) of the RGO-Gr is increased from 22 to 1008. Meanwhile, the response of the RGO-Gr gas sensor is better than that of either a pristine graphene or RGO gas sensor. It is found that the RGO reduction time is related to the content of functional groups that directly reflect on the gas sensing properties of the sensor. The RGO-Gr gas sensor with 10 min reduction time has the best gas sensing properties in this type of sensor. The highest sensitivity is 2.88% towards 0.5 ppm, and the ammonia gas detection limit is calculated to be 36 ppb.

Due to the theoretical importance and potential applications of fullerene, numerous fullerene derivatives have been developed to enhance its solubility and processability. This article provides an overview on fullerene containing polymers, from synthesis to their physicochemical properties in solution. Due to the unique chemical structure of fullerene, different fullerene containing polymeric architecture can be synthesized through various kinds of conjugating techniques, where fullerene can be located either on the backbone or the branch chain. Recently, the successful development of azido coupling and atom transfer radical addition (ATRA) makes it possible to synthesize "controlled" and well-defined fullerene containing polymers. Experimental results indicated that fullerene containing polymers not only increase the solubility of fullerene in solution, but also retain the conjugating properties of fullerene molecules. By blocking well-defined functional polymers onto fullerene molecules, different types of stimuli-responsive amphiphilic systems can be achieved. However, the large bulk volume and high hydrophobicity of fullerene gives rise to the large aggregates with different morphologies produced in solution, which can be tuned by changing external stimuli, such as pH, temperature, salt, and co-solvents. Interestingly, fullerene containing anionic polymers could induce the formation nano-scale fractal pattern, but not fullerene containing cationic polymers, which is evident from morphological studies.

No abstract