In this paper, two newly explored TiO2 photocatalyst sensitized with commercial stable pigment (BYH3G and PR254) were prepared and characterized by FT–IR, UV–Vis, XRD and N2 adsorption-desorption isotherms. The adsorption capacities and the photocatalytic activities of as-prepared photocatalysts were evaluated by photocatalytic degradation of Methyl Orange and Rhodamine B under visible light irradiation. The as-prepared photocatalysts displayed high visible light photocatalytic activity than pure TiO2 under the same conditions. The photocatalytic activity can be reproduced commendably demonstrates that the as-prepared photocatalysts are stable and renewable, which are potentially important properties in the application of industrial wastewater treatment.
A fibrous monolith cemented carbide with WC-6%Co as cell and WC-20%Co as cell boundaries was produced through hot co-extrusion process in this paper. The density, hardness, transverse rupture strength (TRS) and fracture toughness (KIc) of the fibrous monolith cemented carbide were tested, and the fracture and crack propagation were observed by metalloscope and Scanning Electron Microscope. The result shows fibrous monolith structure design could effectively improve the TRS and the KIc of WC/Co cemented carbide without a significant decrease of hardness. It is the reason of high transverse rupture strength and fracture toughness that WC-20%Co can absorb more fracture energy in order to slow, prevent, or deflect crack propagation, proved by metalloscope and scanning electron microscope.
The ignition and combustion characteristics of the fibre-reinforced phenolic composite were studied experimentally employing cone calorimeter. Various parameters, including the ignition time, the mass loss and mass loss rate (MLR), the heat release rate (HRR) and the concentration of the carbon dioxide and carbon monoxide were measured and presented. Linear correlations of the transformed ignition time (1/tig)0.55 and 1/tig, the first and second peak MLR, the average MLR and the peak HRR with the heat flux were demonstrated. Based upon the correlations and theoretical analyses, flammability properties including the critical heat flux (CHF) and the minimum heat flux, the ignition temperature, the heat of gasification and the heat of combustion were calculated. The specimen with the thickness of 3 mm was prone to be thermally thin material. The peak concentration of the carbon dioxide increased with the heat flux. However, the peak concentration of the carbon monoxide declined with an increase in the applied heat flux.
The experiments for treating the pesticide wastewater, which had been produced by Shandong pesticide factory when it produced the Nicosulfuron, were carried out. Through the small test, treatment of pesticide wastewater by batch distillation was studied. The results showed that the top temperature of the recovery samples were about from 98.5°C to 100.2°C,the COD of the recovery samples were about from 10000mg/L to 200 mg/L.With the increasing of the reflux ratio, the average of the COD of these samples and the recoveries reduced gradually, and the removal rate of COD increased gradually, which is above 92% when R≥4.
ZnS/TiO2/Chitosan nanocomposite thin films were prepared by entrapping zinc ions and nanosized TiO2 in chitosan films under mild conditions. The surface structure and morphology of the film were characterized by X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Methyl Orange was selected to evaluate the photocatalytic activity under simulated solar irradiation. The HRTEM results show that TiO2 and ZnS were dispersed uniformly with diameters of 20–30 nm. The prepared film exhibits high photocatalytic activities. About 93.5% Methyl Orange(3.6×10-5 mol/L) were photodegraded by 0.6 g L−1 photocatalyst at pH 4.0 with 120 min irradiation. The influence of the reaction pH, stability and reusability of the film have also been investigated. It can be developed as a economically feasible and environmentally friendly photocatalyst for the practical industrial waste water treatment.
The hydroxyl alumina impregnated weakly basic resin composite (D301Al) successfully prepared through incorporation of hydroxyl alumina into the D301 resin for 2-naphthalenesulfonic acid (2-NSA) removal from aqueous solution. The structure of D301Al was examined using scanning electron microscopy and Fourier transform infrared spectroscopy. The adsorption behaviors of 2-NSA on D301Al were investigated by static adsorption experiments. Effects of pH of solution, temperature and contact time were determined. The results indicated D301Al reached the maximum adsorption capacity to 2-NSA with pH 2.4. Nonlinear regression was used to estimate of Langmuir and Freundlich model parameters. And the Langmuir model can give a satisfactory fit of the experimental equilibrium data. The kinetic studies indicated that the adsorption of D301Al for 2-NSA can establish adsorption equilibrium at 8 h. The pseudo-first-order and pseudo-second-order rate models could characterize the kinetic data of 2-NSA adsorption on D301Al.
The adsorptive behavior of As(V) by using Fe-loaded D301(D301-Fe) was investigated under various conditions. The results indicated that As(V) strongly adsorbed at pH<10. Adsorption isotherm data could be better interpreted by Langmuir model. The kinetic data of the adsorption could be well described by the Lagergren second-order rate equation. equimolar addition of other anionic species such as SO2- 4, Clˉ and Fˉ had no influence on the adsorption of As(V), but PO3- 4 had a strong inhibition on As(V)
Incremental PID has its shortcomings: great integral truncation effect, static error and spillover affect. In the control system, the controller system is required having a quick response speed, and also a certain anti-interference ability. When adopting the improved differential PID control algorithm, only the output differential is made, instead of the given values. So, when a given value changes, the output will not change, and the controlled quantity change is usually mild, in which case the control accuracy is improved, and the system dynamic characteristics is greatly improved.
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