Although a prototypical Su–Schrieffer–Heeger (SSH) soliton exhibits various important topological concepts including particle-antiparticle (PA) symmetry and fractional fermion charges, there have been only few advances in exploring such properties of topological solitons beyond the SSH model. Here, by considering a chirally extended double-Peierls-chain model, we demonstrate novel PA duality and fractional charge e/2 of topological chiral solitons even under the chiral symmetry breaking. This provides a counterexample to the belief that chiral symmetry is necessary for such PA relation and fractionalization of topological solitons in a time-reversal invariant topological system. Furthermore, we discover that topological chiral solitons are re-fractionalized into two subsolitons which also satisfy the PA duality. As a result, such dualities and fractionalizations support the topological $$\mathbb {Z}_4$$ Z 4 algebraic structures. Our findings will inspire researches seeking feasible and promising topological systems, which may lead to new practical applications such as solitronics.