The SnIV atom in the title compound, [Sn(C6H5)3Cl(C13H12OS)], is situated within a distorted C3ClO trigonal–bipyramidal coordination geometry with a mean Sn—C distance of 2.136 (6) Å and with an Sn—O distance of 2.393 (4) Å. The SnIV atom lies 0.171 (3) Å out of the equatorial C3 plane in the direction of the axially bound Cl atom.
The SnIV atom in the title compound, [Sn(C6H5)2Cl2(C13H12OS)], displays a distorted C2Cl2O trigonal–bipyramidal coordination environment, with a mean Sn—C distance of 2.121 (9) Å and with Sn—O = 2.331 (2) Å. The SnIV atom is displaced by 0.169 (2) Å from the equatorial C2Cl plane towards the direction of the second axially bonded Cl atom.
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