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Although high quantum efficiency has been achieved in large-sized InGaN/GaN LEDs operating at relatively high current densities (above 35 A/cm 2 ), the operating current density of mini-LEDs (around 1 A/cm 2 ) is far less than that of traditional large-sized LEDs. The low external quantum efficiency (EQE) of mini-LEDs at small current densities seriously hinders their practical applications, highlighting the importance of investigating the radiative recombination mechanisms of mini-LEDs at small current densities. By using microscopic hyperspectral imaging, the cryogenic electroluminescence (EL) of GaN-based green mini-LEDs mainly originating from localized excitons was demonstrated experimentally. Based on the dependence of electron−phonon coupling on current and temperature, Coulomb screening of the polarization field weakens the electron−phonon coupling, whereas the band-filling effect enhances the coupling. Coulomb screening of the polarization field can also reduce the deviation of the localization. The EL from edge regions of the mesa adjacent to the sidewall possesses relatively higher peak energy due to the strain relaxation. Results of this work also suggest that optimization of the chromatic characteristics and efficiency can be achieved by strain engineering of GaN-based green mini-LEDs.

The anomalous droop in the external quantum efficiency (EQE) induced by the localization of excitons in GaN/InGaN green micro-light-emitting diodes (micro-LEDs) has been demonstrated at temperatures ranging from 25 to 100 K. At cryogenic temperatures, the random distribution of excitons among local potential energy minima limits the radiative recombination and reduces the EQE of green micro-LEDs. As the temperature increases from 25 to 100 K, the hopping of excitons from shallow potential energy minima to the potential energy valley contributes to the enhancement of radiative recombination. The distribution of excitons among local potential energy minima at cryogenic temperatures is also affected by the current density due to the influence of Coulomb screening of the polarization field and the band-filling effect.

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