The development of efficient homogeneous water oxidation catalysts (WOCs) is an important issue for the hydrogen production via water splitting. Copper complexes with well-defined structures are widely studied but the...
Water oxidation is the bottleneck of water splitting, which is a promising strategy for hydrogen production. Therefore, it is significant to develop efficient water oxidation catalysts. Herein, electrochemical water oxidation...
Herein, electrochemical water oxidation catalyzed by a binuclear copper complex [Cu2(MePy3P)2] (1, MePy3PH2 = N,N′-bis[2-(2-pyridyl)methyl]pyridine-2,6-dicarbox-amide) with helical structure is reported. Oxygen evolution occurs with low onset overpotential of 483 mV,...
A stable water-soluble mononuclear manganese clathrochelate complex [MnIV(L-6H)]2- is utilized as electrocatalyst for water oxidation in phosphate buffer solution at pH 8.0. Kinetic tests and electrochemical examinations reveal that this...
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