Hierarchical TiO2 nanotube arrays grown on Ti foil are yielded by subjecting electrochemically anodized, vertically oriented TiO2 nanotube arrays to hydrothermal processing. The resulting DSSCs exhibit a significantly enhanced power conversion efficiency of 7.24%, which is a direct consequence of the synergy of higher dye loading, superior light-scattering ability, and fast electron transport.
Fe−N−C electrocatalysts have been demonstrated to be the most promising substitutes for benchmark Pt/C catalysts for the oxygen reduction reaction (ORR). Herein, we report that N‐doped carbon materials with trace amounts of iron (0–0.08 wt. %) show excellent ORR activity and durability comparable and even superior to those of Pt/C in both alkaline and acidic media without significant contribution by the metal sites. Such an N‐doped carbon (denoted as N‐HPCs) features a hollow and hierarchically porous architecture, and more importantly, a noncovalently bonded N‐deficient/N‐rich heterostructure providing the active sites for oxygen adsorption and activation owing to the efficient electron transfer between the layers. The primary Zn‐air battery using N‐HPCs as the cathode delivers a much higher power density of 158 mW cm−2, and the maximum power density in the H2−O2 fuel cell reaches 486 mW cm−2, which is comparable to and even better than those using conventional Fe−N−C catalysts at cathodes.
Hierarchical Cu2S microspheres wrapped by reduced graphene oxide (RGO) nanosheets are prepared via a one‐step solvothermal process. The amount of graphene oxide used in the synthesis process has a remarkable effect on the features of Cu2S microspheres. Compared to Pt and Cu2S electrodes, RGO‐Cu2S electrodes show better electrocatalytic activity, greater stability, lower charge‐transfer resistance, and higher exchange current density. As expected, RGO‐Cu2S electrodes exhibit superior performance when functioning as counter electrodes in CdS/CdSe quantum dot‐sensitized solar cells (QDSSCs) using a polysulfide electrolyte. A power conversion efficiency up to 3.85% is achieved for the QDSSC employing an optimized RGO‐Cu2S counter electrode, which is higher than those of the QDSSCs featuring Pt (2.14%) and Cu2S (3.39%) counter electrodes.
Recently, hybrid carbon materials and inorganic nanocrystals have received an intensive amount of attention and have opened up an exciting new field in the design and fabrication of high-performance catalysts. Here we present a novel kind of hybrid counter electrode (CE) consisting of a carbon fiber (CF) and Co9S8 nanotube arrays (NTs) for fiber-shaped flexible quantum dot-sensitized solar cells (QDSSCs). The growth mechanisms of Co(CO3)0.35Cl0.20(OH)1.10 nanowire arrays (NWs) on the CFs were discussed, and the catalytic activity of the CF, Pt and Co9S8/CF hybrid structure (Co9S8@CF) were elucidated systematically as well. An absolute energy conversion efficiency of 3.79% has been demonstrated under 100 mW cm(-2) AM 1.5 illumination by using Co9S8@CF as a CE. This work not only demonstrates an innovative approach for growing cobalt sulfide NTs on flexible substrates that can be applied in flexible devices for energy harvesting and storage, but also provides a kind of hybrid structure and high-efficiency CE for QDSSCs.
Peachlike rutile TiO 2 microsphere films were successfully produced on transparent conducting fluorinedoped tin oxide substrate via a facile, one-pot chemical bath route at low temperature (T = 80−85°C) by introducing polyethylene glycol (PEG) as steric dispersant. The formation of TiO 2 microspheres composed of nanoneedles was attributed to the acidic medium for the growth of 1D needle-shaped building blocks where the steric interaction of PEG reduced the aggregation of TiO 2 nanoneedles and the Ostwald ripening process. Dye-sensitized solar cells (DSSCs) assembled by employing these complex rutile TiO 2 microspheres as photoanodes exhibited a light-to-electricity conversion efficiency of 2.55%. It was further improved to a considerably high efficiency of 5.25% upon a series of post-treatments (i.e., calcination, TiCl 4 treatment, and O 2 plasma exposure) as a direct consequence of the well-crystallized TiO 2 for fast electron transport, the enhanced capacity of dye loading, the effective light scattering, and trapping from microstructures.
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