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This article presents a second-law analysis for the use of organic Rankine cycle (ORC) to convert waste energy to power from low-grade heat sources. The organic working fluids were selected to investigate the effect of the fluid boiling point temperature on the performance of ORCs. The working fluids under investigation are R134a, R113, R245ca, R245fa, R123, isobutane, and propane, with boiling points between 243 and 48 °C. The results are compared with those of water under similar conditions. A combined first- and second-law analysis is performed by varying some system operating parameters at various reference temperatures. Some of the results demonstrate that ORC using R113 shows the maximum efficiency among the evaluated organic fluids for temperatures >430 K; R123, R245ca, and R245fa show the best efficiencies for temperatures between 380 and 430 K; and for temperatures <380 K, isobutane shows the best efficiency. Also, it is shown that the organic-fluid boiling point has a strong influence on the system thermal efficiency.

SUMMARYThe exergy topological method is used to present a quantitative estimation of the exergy destroyed in an organic Rankine cycle (ORC) operating on R113. A detailed roadmap of exergy flow is presented using an exergy wheel, and this visual representation clearly depicts the exergy accounting associated with each thermodynamic process. The analysis indicates that the evaporator accounts for maximum exergy destroyed in the ORC and the process responsible for this is the heat transfer across a finite temperature difference. In addition, the results confirm the thermodynamic superiority of the regenerative ORC over the basic ORC since regenerative heating helps offset a significant amount of exergy destroyed in the evaporator, thereby resulting in a thermodynamically more efficient process. Parameters such as thermodynamic influence coefficient and degree of thermodynamic perfection are identified as useful design metrics to assist exergy-based design of devices. This paper also examines the impact of operating parameters such as evaporator pressure and inlet temperature of the hot gases entering the evaporator on ORC performance. It is shown that exergy destruction decreases with increasing evaporator pressure and decreasing turbine inlet temperatures. Finally, the analysis reveals the potential of the exergy topological methodology as a robust technique to identify the magnitude of irreversibilities associated with real thermodynamic processes in practical thermal systems.

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This paper presents a second law analysis and optimization for the use of Organic Rankine Cycle “ORC” to convert waste energy to power from low grade heat sources. The working fluids used in this study are organic substances which have a low boiling point and a low latent heat for using low grade waste heat sources. The organic working fluids under investigation are R134a and R113 and their results are compared with those of ammonia and water under similar operating conditions. A combined first and second law analysis is performed by varying some system operating parameters at various reference temperatures. Some of the results show that the efficiency of ORC is typically below 20% depending on the temperatures and matched working fluid. In addition, it has been found that organic working fluids are more suited for heat recovery than water for low temperature applications, which justifies the use of organic working fluids at the lower waste source temperatures.

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This paper presents an optimization of Organic Rankine Cycles "ORC" using dry organic fluids, to convert waste energy to power from low grade heat sources. The dry organic working fluids under investigation are R113, R245ca, R123, and Isobutene. Different configurations such as reheat ORC and regenerative ORC will be analyzed and compared with the basic ORC in order to determine the configuration that presents the best performance. The optimization for the different configurations will be performed using a combined first and second law analysis by varying some system operating parameters at various reference temperatures and pressures. Some of the results show that regenerative ORC produces higher efficiency compared with the basic ORC while also reducing the amount of waste heat needed to produce the same power with a less irreversibility.