The purpose of this study soil samples were to investigate of Zinc concentrations on the mechanism of adsorption phenomena in four calcareous soils (Choman, Qoshtepe, Herir, and Soran) from Erbil North Iraq classified (calciorthids). Isotherm adsorption was studied by using the Batch technique, 2 g soil was shaken with 40 ml 0.01M CaCl2 containing Zn concentrations of 0, 1, 2, 4, 8, 16, 32, 64, 128, and 256 mg Zn l-1 for 24 hours at 298K. Zn adsorption under isotherm reaction 298K. The adsorption data were described by using Langmuir and Freundlich equations. The results showed that the concentration of adsorption was increased by an increase of Zn level added to Soils. According to the Langmuir equation, the maximum adsorption capacity of Zn was higher in Qoshtepe, Herir Soils. 666 mg kg−1 while the lower value was recorded in Soran soil. Bonding energy was higher in Soran 0.4050 mg L−1, while the lower value was recorded in Choman Soils. 0.0184 mg L-1 soil MBC was higher in Soran Soil. 134.87 mg kg−1 while the lower value was recorded in Choman 7.65 soil, also the results showed that reaction was spontaneous with Negative free energy, were higher in Soil. -2.16 while the lower value was recorded in Herir soil -1.94 joule.mole−1.degree-1 for Soil. And RL value was higher in Choman Soil 0.71, while the lower value was recorded in Soran soil 0.32. The values of qm constant Dubinin-Radushkevich (D-R isotherm) which is the adsorption capacity mol g−1 ranged from -2.3007 to -3.6758
Phosphorus is the second macronutrient which is vital for plants normal growth. In the calcareous soils, the adsorption is the main process that controls P availability to plants. This paper reviews the P adsorption phenomenon in the calcareous soils of Iraqi Kurdistan. In this study, the P adsorption capacity of the selected soils was determined by adding 10 mL of 0, 50, 100, and 200 mg P L-1 as (KH2PO4) to 1.0 g of soil and shaken for 12, 24 and 48 hours on horizontal shaker constantly. The suspensions at each period of incubation centrifuged and filtered then 1nalysed for P which represented the equilibrium P concentration. The minimum adsorption 4.42±0.44 mg kg-1 was recorded for soil4 with 50 mg P L-1 applied solution and 12 h of incubation while the maximum adsorption 124±0.05 mg Kg-1 was recorded for soil3 with 200 mg P L-1 applied solution at 48 h of incubation. These results indicate that P adsorption increased with increasing applied amount of P and time of incubation. Results also showed that the Freundlich model was the best fitted according to the greater values of R2 which was ranged from 0.7619 to 0.9984 compared to 0.738-0.9882 for Langmuir model and 0.7171-0.9986 for Temkin model. These results also suggest that in the studied soils P adsorbed through physical adsorption rather than chemical reaction and then decrease P availability in soil.
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