The synthesis of a Ir(III)-Co(III) dyad with vectorial electron transfer afforded a novel supramolecular system that photocatalytically produces hydrogen in a range extending from the blue region of the spectrum to the red region with higher turnover number and frequency compared to other bimetallic dyads.

We report several new dyads constituted of cationic iridium(iii) photosensitizers and cobalt(iii) catalyst connected via free pendant pyridine on the photosensitizers.

No abstract

No abstract