New red luminescent powders of La(1-x)Pr(x)Sr2AlO5 (x = 0.01 at.) were prepared by the combustion synthesis method. Microstructural properties were characterized by using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The La(1-x)Pr(x)Sr2AlO5 X-ray diffraction pattern revealed a tetragonal phase. Morphology of the grains showed nanobars with sizes of approximately 550 nm in length. Photoluminescence, cathodoluminescence and diffuse reflectance were analyzed in detail. Photoluminescence revealed two narrow emission peaks located at lambda(em1) = 497 nm (green) and lambda(em2) = 620 nm and a single maximum excitation peak of lambda(ex) = 287 nm. The cathodoluminescence spectrum confirmed the peaks detected by photoluminescence analysis. The absorbance spectrum showed broad absorption with a maximum around lambda = 280 nm, which agrees with the maximum excitation peak detected by photoluminescence.
New iron-zinc chlorine single crystals of Fe1.5Zn1.5B7O13Cl boracite were grown by chemical transport reactions in closed quartz ampoules, at a temperature of 1173 K. The crystal structure was characterized by X-ray powder diffraction (XRD) using the Rietveld refinement method and belongs to the trigonal/rombohedral system with space group R3c (No. 161). The cell parameters were a = 8.5726(1) angstroms, c = 21.0116(4) angstroms, V = 1337.26(3) angstroms3 and Z = 6. The refinement successfully proceeded and ended with sound merit figure values chi2 = 2.25, R(B) = 6.12%. Chemical analysis was performed with X-ray energy dispersive spectroscopy (EDS) and X-ray fluorescence (XRF). Ferroelectric nano and micro reoriented domains were found in this material using polarizing optical microscopy (PLM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The examination by TEM showed that in the trigonal/rombohedral system of Fe1.5Zn1.5B7O13Cl nanodomain structures exist. Thin (50-100 nm) mostly planar domains parallel to (100) were frequently observed in Fe1.5Zn1.5B7O13Cl boracite.
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