In this article, we demonstrate the
fabrication of tailored multicomponent
cryoaerogels from colloidal nanoparticles via the cryogelation method.
With this method, it is possible to control the amount of components
very precisely. Furthermore, the microscopic distribution of the different
nanoparticle components in the resulting monolithic structure is shown
to be adjustable by simply mixing calculated amounts of colloidal
nanoparticle solutions with a suitable surface charge. We focus on
titania cryoaerogels due to their potential for optical applications
and investigate the properties of synthesized titania-gold cryoaerogels
in dependency of the composition. In addition, titania-platinum cryoaerogels
were tested for photocatalytic applications such as hydrogen evolution
and showed a significant increase in performance and stability compared
to their respective colloidal solutions. While showing comparable
results for hydrogen evolution with aerogels as reported in literature,
the fabrication is much faster and less complex and therefore might
enable future industrial application.
Halide perovskites are a promising optical gain medium with high tunability and simple solution synthesis. In this study, two gain regimes, namely, amplified spontaneous emission and random lasing, are demonstrated in the same MAPbBr3 halide perovskite single crystal. For this, photoluminescence is measured at a temperature of 4 K with pulsed femtosecond pumping by UV light with an 80 MHz repetition rate. Random lasing is observed in areas of the sample where a random resonator is formed due to cracks and crystal imperfections. In more homogeneous regions of the sample, the dominant regime is amplified spontaneous emission. These two regimes are reliably distinguished by the line width, the mode structure, the growth of the intensity after the threshold, and the degree of polarization of the radiation. The spectral localization of the stimulated emission well below the bound exciton resonance raises a question concerning the origin of the emission in halide perovskite lasers.
For
the understanding of the activity of TiO2 photocatalysts,
knowledge of the activities of different crystal facets is necessary.
This information can be achieved by the investigation of well-defined
single-crystalline TiO2 surfaces. In this study, the photocatalytic
activity of different anatase, brookite, and rutile single-crystal
wafers with only one exposed surface has been investigated via the
oxidation of methanol and the hydroxylation of terephthalic acid,
respectively. X-ray diffraction, atomic force microscopy, and scanning
electron microscopy measurements have shown that all surfaces are
clearly defined and possess a smooth surface, which allows a reliable
comparison of the photocatalytic activities. The investigated anatase
surfaces show higher activity than the rutile surfaces, while the
brookite surface is interestingly the least active one. To the best
of our knowledge, there are no other reports based on the investigation
and comparison of well-defined TiO2 anatase (100), anatase
(001), and brookite (100) single-crystalline surfaces concerning their
photocatalytic activity. Furthermore, the influence of the coordination
of the superficial titanium and the oxygen ions on the photocatalytic
activity is discussed.
In our work, we employed Cs3Bi2I9 as a visible-light-active photocatalyst, synthesized with a low-temperature solvothermal method. The morphological and structural properties of the as-prepared perovskite were investigated, and the results were compared to previous studies to confirm its nature and the quality of the synthesis procedure. Transient absorption spectroscopy was applied in order to investigate the generation and lifetime of photogenerated charge carriers, revealing their formation after visible light excitation. The potential photocatalytic activity of the as-prepared metal halide perovskite was applied for the removal of Rhodamine B in aqueous solution, demonstrating an excellent activity of 93% after 180 min under visible-light irradiation. The current research aims to provide insights into the design of a new visible-light-active photocatalyst, Cs3Bi2I9, selected for its high application value in the field of advanced materials for light harvesting.
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